51010-88-9

Basic information

• Product Name: 2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)-
• CAS NO: 51010-88-9
• Molecular Formula: C7H9BrO2
• Molecular Weight: 205.051
• Mol File: 51010-88-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)-(51010-88-9)
• EPA Substance Registry System: 2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)-(51010-88-9)

Safety Data

• Hazardous Substances Data: 51010-88-9(Hazardous Substances Data)

Usage

General Description

2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)- is a chemical compound with the molecular formula C8H11BrO2. It is the methyl ester form of 6-bromo-2,4-hexadienoic acid, with the double bonds in the E,E configuration. 2,4-Hexadienoic acid, 6-bromo-, methyl ester, (E,E)- is used in various chemical and pharmaceutical applications, including as a building block in the synthesis of organic compounds. It is also known to have potential biological activity, making it of interest in the development of new drugs and pharmaceuticals. Additionally, it is important to handle this compound with care, as it may have hazardous or irritating effects on human health and the environment.

Upstream product

• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 128-08-5 N-Bromosuccinimide 
• 56-23-5 tetrachloromethane 
• 94-36-0 dibenzoyl peroxide 
• 110-44-1 sorbic Acid 
• 106-95-6 allyl bromide 
• 31930-39-9 4-bromocrotonaldehyde 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 1515-80-6 sorbic acid methyl ester 

Downstream Products

• 51276-40-5 5-methoxycarbonylpenta-2E,4E-dienyltriphenylphosphonium bromide 
• 91890-23-2 C₂₂H₂₅NO₄S 
• 17157-48-1 bromoacetaldehyde 
• 698387-80-3 methyl (2E,4E)-6-(4-methoxyphenylsulfanyl)-2,4-hexadienoate 
• 698387-77-8 methyl (2E,4E)-6-phenylsulfanyl-2,4-hexadienoate 
• 698387-81-4 6-(4-chlorophenylsulfanyl)-hexa-2,4-dienoic acid hydroxyamide 
• 698387-84-7 methyl (2E,4E)-6-(4-methoxybenzenesulfinyl)-2,4-hexadienoate 
• 81454-76-4 methyl (2E,4E)-4-(phenylsulphinyl)hexa-2,4-dienoate 
• 200798-57-8 Benzoic acid (2E,4E)-5-methoxycarbonyl-penta-2,4-dienyl ester 
• 98136-01-7 6-Hydroxy-trans,trans-2,4-hexadienoic acid 
• 1579963-91-9 (2E,4E)-methyl 6-(4-bromo-2-formylphenoxy)hexa-2,4-dienoate 
• 1579963-92-0 (2E,4E)-methyl 6-(2,4-dichloro-6-formylphenoxy)hexa-2,4-dienoate 

Relevant articles and documents

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A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon

A highly efficient method for the enantioselective synthesis of 1,4-dienes (skipped dienes) with a methyl-substituted central stereogenic carbon using copper-catalysed asymmetric allylic alkylation of diene bromides was developed. Excellent regio- and enantioselectivity (up to 97 : 3 SN2′/ SN2 ratio and 99% ee) were achieved with broad substrate scope. The Royal Society of Chemistry 2013.

Ruthenium-catalyzed regio- and enantioselective allylic substitution with water: Direct synthesis of chiral allylic alcohols

Less is more: A new route to access chiral allylic alcohols through the regio- and enantioselective substitution of monosubstituted allylic chlorides with water has been developed. The reaction is catalyzed effectively by planar-chiral cyclopentadienyl ruthenium complexes (see scheme). Copyright