51224-17-0

Basic information

• Product Name: 6-AMINOHEXYL-N-ACETYL-B-D-THIOGLUCOSAMIN IDE
• Synonyms: 6-AMINOHEXYL-N-ACETYL-B-D-THIOGLUCOSAMIN IDE;6-aminohexyl N-acetyl-beta-D-thioglucosaminide;6-Aminohexyl 2-acetamido-2-deoxy-1-thio-β-D-glucopyranoside;6-Aminohexyl N-acetyl-β-D-thioglucosaminide
• CAS NO: 51224-17-0
• Molecular Formula: C14H27N2O5S-
• Molecular Weight: 335.43958
• Mol File: 51224-17-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 6-AMINOHEXYL-N-ACETYL-B-D-THIOGLUCOSAMIN IDE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-AMINOHEXYL-N-ACETYL-B-D-THIOGLUCOSAMIN IDE(51224-17-0)
• EPA Substance Registry System: 6-AMINOHEXYL-N-ACETYL-B-D-THIOGLUCOSAMIN IDE(51224-17-0)

Safety Data

• Hazardous Substances Data: 51224-17-0(Hazardous Substances Data)

Upstream product

• 77346-20-4 Acetic acid (2R,3S,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-5-acetylamino-6-[6-(2,2,2-trifluoro-acetylamino)-hexylsulfanyl]-tetrahydro-pyran-4-yl ester 
• 73982-52-2 2-Acetamino-3,4,6-tri-O-acetyl-1,2-bisdesoxy-1-S-isothioureido-β-D-glucopyranose 
• 4048-33-3 6-amino-1-hexanol 
• 40248-34-8 6-trifluoroacetamido-1-hexanol 
• 51224-10-3 1-iodo-6-(trifluoroacetamido)hexane 

Relevant articles and documents

PREPARATION OF ANOMERIC PAIRS OF 1-THIOGLYCOSIDES: USE OF ANOMERIZATION CATALYZED BY BORON TRIFLUORIDE

Anomeric pairs of some alkyl 1-thioaldopyranosides of D-galactose, D-glucose, D-mannose, 2-acetamido-2-deoxy-D-glucose, 2-acetamido-2-deoxy-D-galactose, and L-fucose were prepared.The per-O-acetylated, 1,2-trans anomers of 6-(trifluoroacetamido)hexyl 1-thioaldopyranosides and 5-(methoxycarbonyl)pentyl 1-thioaldopyranosides were anomerized with boron trifluoride in dichloromethane.The anomeric mixtures were then separated by chromatography, using columns of either silica gel or an ion-exchange resin.De-blocking of the separated compounds provided pure anomers of 6-aminohexyl 1-thioaldopyranosides or 5-carboxypentyl 1-thioaldopyranosides.The aglycons of the latter glycosides were further extended by reaction with aminoacetaldehyde diethyl acetal, which, after deacetalization of the products, provided an ω-aldehydo group.These series of glycosides could be readily coupled to proteins or solid matrices.