51231-09-5

Basic information

• Product Name: 4-Pentenoic acid, phenyl ester
• CAS NO: 51231-09-5
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 51231-09-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-Pentenoic acid, phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Pentenoic acid, phenyl ester(51231-09-5)
• EPA Substance Registry System: 4-Pentenoic acid, phenyl ester(51231-09-5)

Safety Data

• Hazardous Substances Data: 51231-09-5(Hazardous Substances Data)

Upstream product

• 620-72-4 phenyl 2-bromoacetate 
• 33574-02-6 cyclopropylmethyl iodide 
• 201230-82-2 carbon monoxide 
• 108-95-2 phenol 
• 5162-44-7 1-bromo-4-butene 
• 591-80-0 pent-4-enoic acid 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 

Downstream Products

• 1454661-17-6 phenyl 5-(diethoxyphosphoryl)-4-fluoropentanoate 
• 1300026-54-3 (R,Z)-phenyl 7-((tert-butyldimethylsilyl)oxy)-6-(1,3-dioxoisoindolin-2-yl)hept-4-enoate 
• 591-80-0 pent-4-enoic acid 
• 108-95-2 phenol 

Relevant articles and documents

Palladium-Catalyzed Linear Hydrothiocarbonylation of Unactivated Terminal Alkenes: Synthesis of Aliphatic Thioesters

A Pd-catalyzed hydrothiocarbonylation of unactivated terminal alkenes is presented. According to this protocol, aliphatic thioesters were synthesized with exclusive linear selectivity under mild reaction conditions. Good to excellent yields (up to 91% yie

The insertion of arynes into the O-H bond of aliphatic carboxylic acids

The insertion of arynes into the O-H bond of aliphatic carboxylic acids promoted by sodium carboxylates is described. The reactions led to the formation of aryl carboxylates in good yields with good chemoselectivities under mild conditions.

'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions

A new generation of propylene-spaced fluorous allyltin reagents [(Rf(CH2)3)3SnCH2CH=CH2] is described. These succeed in radical allylations where their lower homologs (ethylene-spaced) fail, and they provide improved performance in transition metal catalyzed allylations. The reagents and byproducts are readily separated by simple fluorous-organic liquid-liquid or solid-liquid extractions.