51317-78-3

Basic information

• Product Name: (1S,2S)-2-formylamino-1-phenyl-1,3-propanediol
• Synonyms: (1S,2S)-2-formylamino-1-phenyl-1,3-propanediol
• CAS NO: 51317-78-3
• Molecular Weight: 195.218
• Mol File: 51317-78-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2S)-2-formylamino-1-phenyl-1,3-propanediol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-2-formylamino-1-phenyl-1,3-propanediol(51317-78-3)
• EPA Substance Registry System: (1S,2S)-2-formylamino-1-phenyl-1,3-propanediol(51317-78-3)

Safety Data

• Hazardous Substances Data: 51317-78-3(Hazardous Substances Data)

Upstream product

• 107-31-3 Methyl formate 
• 28143-91-1 (1S,2S)-2-amino-1-phenyl-1,3-diol 

Downstream Products

• 35019-66-0 (4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine 
• 102224-22-6 (4S,5S)-5-(formylamino)-2,2-dimethyl-4-phenyl-1,3-dioxane 

Relevant articles and documents

New chiral iminium salt catalysts for asymmetric epoxidation

A range of enantiomerically pure 4-substituted 5-amino-1,3-dioxanes has been condensed with 2-(2-bromoethyl)benzaldehyde to produce chiral dihydroisoquinolinium salts, which are effective asymmetric catalysts for the epoxidation of simple alkenes, giving ees of up to 71 %. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

AN IMPROVED SYNTHESIS OF (4S,5S)-2,2-DIMETHYL-4-PHENYL-1,3-DIOXAN-5-AMINE

The title compound is prepared in 78percent yield using an improved one-pot procedure which does not require final purification.