51549-18-9

Basic information

• Product Name: Adenosine, N-(phenylmethyl)-, 2',3',5'-triacetate
• CAS NO: 51549-18-9
• Molecular Formula: C23H25N5O7
• Molecular Weight: 483.481
• Mol File: 51549-18-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Adenosine, N-(phenylmethyl)-, 2',3',5'-triacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Adenosine, N-(phenylmethyl)-, 2',3',5'-triacetate(51549-18-9)
• EPA Substance Registry System: Adenosine, N-(phenylmethyl)-, 2',3',5'-triacetate(51549-18-9)

Safety Data

• Hazardous Substances Data: 51549-18-9(Hazardous Substances Data)

Upstream product

• 28708-32-9 1,2,3,5-tetra-O-acetyl-D-ribofuranose 
• 1214-39-7 6-benzyladenine 
• 108-88-3 toluene 
• 7387-57-7 triacetyladenosine 
• 3181-38-2 2',3',5'-tri-O-acetylinosine 
• 863033-41-4 2',3',5'-tri-O-acetyl-1-(2,4-dinitrobenzenesulfonyl)inosine 
• 100-46-9 benzylamine 
• 74590-27-5 Benzyl-(9-trimethylsilanyl-9H-purin-6-yl)-amine 
• 13035-61-5 1,2,3,5-tetraacetylribose 
• 80585-32-6 N⁶,N⁶-Dibenzyl-2',3',5'-tri-O-acetyladenosine 

Downstream Products

• 4294-16-0 N₆-Benzyladenosine 

Relevant articles and documents

CuI controlled C-C and C-N bond formation of heteroaromatics through C(sp3)-H activation

A new method for C-C and C-N bond formation of heteroaromatics and C(sp3)-H alkanes was developed with high regioselectivity. The reaction occurred on C8 to give 8-cylcoakylpurines by C-C bond formation only promoted by tBuOOtBu, while it occurred on the amino group to give N6-alkylated purines by C-N bond formation when 2 equiv of CuI were added. A reaction mechanism was also proposed based on our preliminary experimental data.

A novel nucleophilic approach to 1-alkyladenosines. A two-step synthesis of [1-15N]adenosine from inosine

A novel ANRORC mechanism in the reaction of 1-(2,4-dinitrobenzenesulfonyl) inosines with amines has allowed the preparation of 1-alkyladenosines and [1-15N]adenosines in a straightforward way from inosines. The Royal Society of Chemistry 2005.

One-pot synthesis of nucleosides using bismuth (III) bromide as catalyst

A peracetylated α-D-ribofuranosyl bromide reacted with silylated heterocyclic bases in the presence of bismuth (III) bromide (a non-toxic catalyst) in a one-pot procedure to give the corresponding β-D-nucleoside in good yield.