51684-92-5

Basic information

• Product Name: (S)-2-Acetylamino-3-naphthalen-1-yl-propionic acid
• Synonyms: (S)-2-Acetylamino-3-naphthalen-1-yl-propionic acid
• CAS NO: 51684-92-5
• Molecular Weight: 257.289
• Mol File: 51684-92-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-2-Acetylamino-3-naphthalen-1-yl-propionic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-Acetylamino-3-naphthalen-1-yl-propionic acid(51684-92-5)
• EPA Substance Registry System: (S)-2-Acetylamino-3-naphthalen-1-yl-propionic acid(51684-92-5)

Safety Data

• Hazardous Substances Data: 51684-92-5(Hazardous Substances Data)

Upstream product

• 3163-27-7 2-(bromomethyl)naphthalene 
• 136015-49-1 2-Acetylamino-2-naphthalen-1-ylmethyl-malonic acid monoethyl ester 
• 5440-57-3 diethyl (N-acetylamino)[(1-naphthyl)methyl]malonate 
• 88681-65-6 (Z)-2-Acetylamino-3-naphthalen-1-yl-acrylic acid 
• 125761-75-3 2-Acetylamino-3-naphthalen-1-yl-propionic acid ethyl ester 

Downstream Products

• 55447-00-2 (S)-2-tert-butoxycarbonylamino-3-naphthalen-1-yl-propionic acid 
• 136015-53-7 (S)-3-[(S)-2-((S)-2-tert-Butoxycarbonylamino-3-naphthalen-1-yl-propionylamino)-hexanoylamino]-N-((S)-1-carbamoyl-2-phenyl-ethyl)-succinamic acid 
• 136015-52-6 (S)-3-[(S)-2-((S)-2-tert-Butoxycarbonylamino-3-naphthalen-1-yl-propionylamino)-hexanoylamino]-N-((S)-1-carbamoyl-2-phenyl-ethyl)-succinamic acid benzyl ester 
• 136039-63-9 (S)-3-{(S)-2-[(S)-2-(2-{(S)-2-[(S)-2-tert-Butoxycarbonylamino-3-(4-hydroxy-phenyl)-propionylamino]-hexanoylamino}-acetylamino)-3-naphthalen-1-yl-propionylamino]-hexanoylamino}-N-((S)-1-carbamoyl-2-phenyl-ethyl)-succinamic acid 
• 136015-56-0 (S)-3-{(S)-2-[(S)-2-(2-{(S)-2-[(S)-2-tert-Butoxycarbonylamino-3-(4-sulfooxy-phenyl)-propionylamino]-hexanoylamino}-acetylamino)-3-naphthalen-1-yl-propionylamino]-hexanoylamino}-N-((S)-1-carbamoyl-2-phenyl-ethyl)-succinamic acid 
• 55516-54-6 L-1-naphthylalanine 

Relevant articles and documents

2,2',5,5'-tetramethyl-4,4'-bis(diphenylphoshino)-3,3'-bithiophene: A new, very efficient, easily accessible, chiral biheteroaromatic ligand for homogeneous stereoselective catalysis

The four-step straightforward synthesis of enantiopure (+)- and (-)- 2,2',5,5'-tetramethyl-4,4'-bis(diphenylphoshino)-3,3'-bithiophene (tetraMe- BITIOP), anew C2-symmetry chelating ligand for transition metals, is described, starting from 2,5-dimethylthiophene. The complexes of this electron-rich diphosphine with Ru(II) and Rh(I) were used as catalysts in some homogeneous hydrogenation reactions of prostereogenic carbonyl functions of α- and β-ketoesters, of prostereogenic carbon-carbon double bonds of substituted acrylic acids, and of N-acetylenamino acids. The enantiomeric excesses were found to be excellent in all the experiments and comparable with the best results reported in the literature for the same reactions, carried out under similar experimental conditions, with the metal complexes of the most popular chiral diphosphine ligands as catalysts.