51833-36-4Relevant articles and documents
Method of preparing organomagnesium compounds
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Page/Page column 6-7, (2010/02/14)
The present invention is directed to a reagent for use in the preparation of organomagnesium compounds as well as to a method of preparing such organomagnesium compounds. The present invention furthermore provides a method of preparing functionalized or unfunctionalized organic compounds as well as the use of the reagents of the present invention in the preparation of organometallic compounds and their reaction with electrophiles. Finally, the present invention is directed to the use of lithium salts - LiY in the preparation of organometallic compounds and their reactions with electrophiles and to an organometallic compound which is obtainable by the disclosed method.
Effective Synthesis of 2-propionic Acid via Hydromagnesation Reaction with Nickel or Titanium Catalysts
Amano, Takehiro,Ota, Tomomi,Yoshikawa, Kensei,Sano, Tatsuhiko,Ohuchi, Yutaka,et al.
, p. 1656 - 1658 (2007/10/02)
2-propionic acid was synthesized in 82percent yield via nickel(II) chloride or dichlorobis5-cyclopentadienyl>titanium-catalyzed hydromagnesation of 1-(3-methyl-2-butenyl)-4-vinylbenzene obtained in ca. 63-68percent yield by the coupling reaction of 4-(3-methyl-2-butenyl)phenylmagnesium chloride with vinyl chloride.