52007-57-5Relevant articles and documents
A convergent, modular access to α-chloro-trifluoromethyl derivatives and to 1,1-difluoroalkenes
Salomon, Pierre,Kosnik, Wioletta,Zard, Samir Z.
, p. 7144 - 7153 (2015)
Abstract An efficient protocol for the preparation of S-(1-chloro-2,2,2-trifluoroethyl)-O-ethyl xanthate is reported. This reagent serves as a versatile precursor of highly functionalized gem-difluoroalkenes through various inter- and intramolecular radical reactions and subsequent reduction with activated magnesium metal.