52251-23-7Relevant articles and documents
Synthesis and anion-selective complexation of cyclophane-based cyclic thioureas
Sasaki, Shin-ichi,Mizuno, Masaaki,Naemura, Koichiro,Tobe, Yoshito
, p. 275 - 283 (2007/10/03)
Cyclic thiourea derivatives having three different types of cyclophane structure, ortho-meta, meta-meta, and meta-para, and a lariat-type thiourea, were synthesized, and their anion-binding ability was examined. The association constants for the complexation between the receptors and several anions in DMSO-d6 were measured by the titration method using 1H NMR spectroscopy. All receptors, except for the meta-para cyclophane, exhibit selective binding to the dihydrogenphosphate anion, which is stronger than that of the acyclic reference compound. The lariat-type receptor binds anions even more strongly than the cyclic receptors which do not possess the third binding site.