52417-38-6Relevant articles and documents
Napthalene-catalysed lithiation of carbamoyl and thiocarbamoyl chlorides under Barbier-type reaction conditions
Ramon, Diego J.,Yus, Miguel
, p. 13739 - 13750 (2007/10/03)
The reaction of different carbamoyl or thiocarbamoyl chlorides 1 with carbonyl compounds or imines 2 in the presence of an excess of lithium powder and a catalytic amount of naphthalene (3 mol %) in THF at -78°C leads, after hydrolysis with water, to the
DESTABILIZED CARBOCATIONS. NUCLEAR MATNETIC RESONANCE DETECTION AND REACTIVITIES OF ARYL α-THIOFORMAMIDYL CATIONS
Ablenas, F. J.,George, B. E.,Maleki, M.,Jain, R.,Hopkinson, A. C.,Lee-Ruff, E.
, p. 1800 - 1803 (2007/10/02)
A series of α-aryl and diarylthioformamidyl cations were observed by low-temperature nuclear magnetic resonance spectroscopy.These ions undergo efficient cyclization and deprotonation to give benzothiophenes.