52922-10-8

Basic information

• Product Name: 2-methyl-1-phenyl-3-buten-1-ol
• Synonyms: 2-methyl-1-phenyl-3-buten-1-ol
• CAS NO: 52922-10-8
• Molecular Weight: 162.232
• Mol File: 52922-10-8.mol
• Article Data: 231

Chemical Properties

• CAS DataBase Reference: 2-methyl-1-phenyl-3-buten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-1-phenyl-3-buten-1-ol(52922-10-8)
• EPA Substance Registry System: 2-methyl-1-phenyl-3-buten-1-ol(52922-10-8)

Safety Data

• Hazardous Substances Data: 52922-10-8(Hazardous Substances Data)

Upstream product

• 4088-60-2 cis-2-buten-1-ol 
• 100-52-7 benzaldehyde 
• 106357-20-4 (R,R)-diisopropyl tartrate (Z)-crotylboronate 
• 99687-40-8 (R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate 
• 18147-55-2 (E)-crotyltrichlorosilane 
• 27299-31-6 (Z)-((but-2-en-1-yloxy)methyl)benzene 
• 18147-55-2 (Z)-crotyltrichlorosilane 
• 35998-93-7 tri-n-butylcrotyltin 
• 35998-94-8 (Z)-crotyltri-n-butylstannane 
• 31197-41-8 crotyltributylstannane 
• 856676-01-2 (10S)-(E)-B-crotyl-10-trimethylsilyl-9-borabicyclo[3.3.2]decane 
• 18147-55-2 but-2-enyltrichlorosilane 
• 4784-77-4 (E)-1-Bromo-2-butene 
• 1311404-15-5 (S)‐2‐(p‐tolylsulfinyl)benzyl 4‐methylbenzenesulfonate 

Downstream Products

• 261919-07-7 (3S,5E)-1-phenyl-5-heptene-3-ol 
• 1392302-92-9 (S)-(-)-O-[2-methyl-1-phenyl-3-butene-1-yl]hydroxylamine 
• 1392303-10-4 (3R,4S,5R)-(+)-N-tert-butoxycarbonyl-3-(methoxycarbonylmethyl)-4-methyl-5-phenylisoxazolidine 
• 1392303-11-5 (3S,4S,5R)-(+)-N-tert-butoxycarbonyl-3-(methoxycarbonylmethyl)-4-methyl-5-phenylisoxazolidine 
• 1392303-22-8 methyl (3S,5R)-(+)-3-(tert-butoxycarbamoyl)-5-hydroxy-3-methyl-5-(phenyl)valerate 
• 1446121-69-2 (3R,6R,7S)-((1S,2S)-2-methyl-1-phenylbut-3-enyl) 3,6,7-trihydroxy-6-methylnon-8-enoate 
• 1446121-81-8 (4R,7R,8S,11S,12S,E)-4,7,8-trihydroxy-7,11-dimethyl-12-phenyl-oxacyclododec-9-en-2-one 
• 1446121-91-0 (2S,3S,6S,7R,10R,E)-7,10-dihydroxy-3,7-dimethyl-12-oxo-2-phenyloxa cyclododec-4-en-6-yl acetate 
• 1446121-59-0 (R)-((1S,2S)-2-methyl-1-phenylbut-3-enyl)-3-(tert-butyldimethylsilyloxy)-5-((4R,5S)-2,2,4-trimethyl-5-vinyl-1,3-dioxolan-4-yl)pentanoate 

Relevant articles and documents

Chiral bronsted acid-catalyzed allylboration of aldehydes

The catalytic enantioselective allylation of aldehydes is a long-standing problem of considerable interest to the chemical community. We disclose a new high-yielding and highly enantioselective chiral Bronsted acid-catalyzed allylboration of aldehydes. Th

Enhancement of threo-Selectivity in the Reaction of But-2-enyl-lithium with Aldehydes via Allylic Boronate Complexes

The threo-selectivity of the reaction of but-2-enyl-lithium with aldehydes in the presence of certain trialkylboranes is enhanced; the corresponding allylic boronate complexes are presumably involved as intermediates.

Kinetic Resolution of α-Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes

We describe the kinetic resolution of α-silyl-substituted allylboronate esters via chiral phosphoric acid-catalyzed chemo-, diastereo- and enantioselective allylboration of aldehydes. This process provides two synthetically versatile enantioenriched compo

Photoredox Ni-Catalyzed Branch-Selective Reductive Coupling of Aldehydes with 1,3-Dienes

We report here a Ni-catalyzed reductive coupling of aldehydes with widely available 1,3-dienes under visible-light photoredox dual catalysis. The homoallyic alcohols are obtained in broad scope with complete branched regioselectivity. Hantzsch ester is used as the hydrogen radical source to oxidize low-valent nickel salt affording Ni-H species. Preliminary mechanistic studies indicate a successive single-electron transfer (SET) pathway and the generation of a key π-allylnickel intermediate via Ni-H insertion of 1,3-diene in this synergistic catalytic process.

A Novel Synthesis of (E)-2-Alkenylborane from Chiral Borane and Diazoalkene: Asymmetric Alkenylboration of Aldehydes

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