53254-60-7

Basic information

• Product Name: Geranyl-p-TolylSulfone
• Synonyms: (E)-1-((3,7-dimethylocta-2,6-dien-1-yl)sulfonyl)-4-methylbenzene;(E)-1-((3,7-dimethylocta-2,6-dien-1-yl)sulfonyl)-4-methylbenzene(WXC06063)
• CAS NO: 53254-60-7
• Molecular Formula: C₁₇H₂₄O₂S
• Molecular Weight: 292.44
• Mol File: 53254-60-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 443.16°C at 760 mmHg
• Flash Point: 254.471°C
• Appearance: /
• Density: 1.034g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: Geranyl-p-TolylSulfone(CAS DataBase Reference)
• NIST Chemistry Reference: Geranyl-p-TolylSulfone(53254-60-7)
• EPA Substance Registry System: Geranyl-p-TolylSulfone(53254-60-7)

Safety Data

• Hazardous Substances Data: 53254-60-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C17H24O2S/c1-14(2)6-5-7-15(3)12-13-20(18,19)17-10-8-16(4)9-11-17/h6,8-12H,5,7,13H2,1-4H3/b15-12+

Upstream product

• 6138-90-5 trans-geranyl bromide 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 141-12-8 neryl acetate 
• 115-95-7 linalool acetate 
• 72863-23-1 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene 
• 119306-02-4 geranyl p-toluenesulfinate 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 106-24-1 Geraniol 

Downstream Products

• 53260-08-5 1-methyl-4-((6E,10E)-2,6,11,15-tetramethyl-hexadeca-2,6,10,14-tetraene-8-sulfonyl)-benzene 
• 53260-09-6 1-methyl-4-((6E,10Z)-2,6,11,15-tetramethyl-hexadeca-2,6,10,14-tetraene-8-sulfonyl)-benzene 
• 66958-23-4 C₅₁H₆₈O₆S₃ 
• 66958-24-5 C₆₈H₉₀O₈S₄ 
• 66958-64-3 1,4-Dimethoxy-2,3,5-trimethyl-6-[(2E,6E,10E)-3,7,11,15-tetramethyl-9-(toluene-4-sulfonyl)-hexadeca-2,6,10,14-tetraenyl]-benzene 
• 66958-21-2 1-((2E,6E)-8-Chloro-3,7-dimethyl-octa-2,6-diene-1-sulfonyl)-4-methyl-benzene 
• 122273-94-3 dimethyl-3,7 methoxy-7 phenylseleno-6 p-toluenesulfonyl-1 octene-2 (E) 
• 95514-61-7 1-((E)-6,10-Dimethyl-undeca-1,5,9-triene-4-sulfonyl)-4-methyl-benzene 
• 73127-51-2 (2E,6E,10E)-3,7,11,15-tetramethyl-9-[(4-methylphenyl)sulfonyl]hexadeca-2,6,10,14-tetraen-1-yl acetate 
• 95682-07-8 4,8-Dimethyl-2-p-tolylsulfonyl-3(E),7-nonadienoic acid 
• 78284-80-7 (2E,6E,10E)-3,7,11-trimethyl-5-p-tolylsulphonyldodeca-2,6,10-trien-1-ol 
• 130487-38-6 (2E,6Z,10E)-1-Benzyloxy-7-benzyloxymethyl-9-(p-tolylsulfonyl)-3,11,15-trimethyl-2,6,10,14-hexadecatetraene 
• 102230-49-9 (6E,10E)-2,6,10-Trimethyl-12-(3-methyl-2-furyl)-8-(4-methylphenylsulfonyl)-2,6,10-dodecatrien 
• 135898-05-4 3,4-dihydro-6-<(2-methoxyethoxy)methoxy>-2-methyl-2-<6-<(4-methylphenyl)sulfonyl>4,8,12-trimethyltrideca-3(E),7(E),11-trienyl>-2H-1-benzopyran 

Relevant articles and documents

SYNTHESES A L'AIDE DE SULFONES. XXIII. SUR LA SELECTIVITE DE LA SYNTHESE DES DULFONES ALLYLIQUES

The role of the palladium ligands on the yield and regioselectivity of the reaction of conjugated dienes with arenesulphinic acids (or of allylic acetates with sodium arenesulphinates) has been investigated.Arenesulphinic acids catalyse the isomerisation of allylic sulphones.

Synthesis of SHIP1-activating analogs of the sponge meroterpenoid pelorol

Two biomimetic approaches have been used to synthesize analogs of the SHIP1-activating sponge meroterpenoid pelorol (1). One approach started from the chiral pool plant natural product sclareolide, which has the same absolute configuration as pelorol. The

Asymmetric Induction Reactions. III. Palladium-Catalyzed Asymmetric Sulfonylations of Allylic Sulfinates and Acetates with Chiral Phosphine Ligands

Treatment of allylic (+/-)-p-toluenesulfinate with tetrakis(triphenlphosphine)palladium in the presence of chiral phosphine ligands resulted in allylic sulfinate-sulfone rearrangements to give the corresponding optically active allylic sulfones in high op