53488-28-1Relevant articles and documents
Selective Nitroxylation of Adamantane Derivatives in the System Nitric Acid–Acetic Anhydride
Ivleva, E. A.,Klimochkin, Yu. N.,Moiseev, I. K.
, p. 1532 - 1539 (2020/10/22)
Abstract: A number of new nitroxyadamantanes have been synthesized by nitroxylation of the corresponding substrates with nitric acid in acetic anhydride. High electrophilicity and reduced acidity of the system HNO3–Ac2O increases the stability of nitrates and significantly decreases the probability of formation of alcohols. In some cases, nitrolysis and oxidation of functional groups in the substrate are observed.
REACTION OF MONOFUNCTIONAL SUBSTITUTED ADAMANTANES WITH NITRIC ACID AND ITS MIXTURES
Moiseev, I. K.,Klimochkin, Yu. N.,Zemtsova, M. N.,Trakhtenberg, P. L.
, p. 1307 - 1309 (2007/10/02)
In the reaction of monofunctional substituted adamantanes with nitric acid and its mixtures the main reaction products are the nitrates of adamantanol, formed either as a result of substitution of the functional groups or as a result of substitution of a hydrogen atom at a tertiary carbon atom.