53531-31-0

Basic information

• Product Name: 9-TRIFLUOROACETYLANTHRACENE
• Synonyms: 9-ANTHRYL TRIFLUOROMETHYL KETONE;9-TRIFLUOROACETYLANTHRACENE;9-(Trifluoroacetyl)antracene;9-ANTHRYL TRIFLUOROMETHYL KETONE, 98+%;9-(TRIFLUOROACETYL)ANTHRACENE 98%;1-(9-Anthracenyl)-2,2,2-trifluoroethanone;Trifluoromethyl(9-anthryl) ketone;9-(Trifluoroacetyl)anthracene,98%
• CAS NO: 53531-31-0
• Molecular Formula: C₁₆H₉F₃O
• Molecular Weight: 274.24
• EINECS: 258-609-4
• Product Categories: Anthracenes;C15 to C38;Carbonyl Compounds;Ketones
• Mol File: 53531-31-0.mol
• Article Data: 7

Chemical Properties

• Melting Point: 84-86 °C(lit.)
• Boiling Point: 386.7°Cat760mmHg
• Flash Point: 189.7°C
• Appearance: Yellow/Powder
• Density: 1.3021 (estimate)
• Vapor Pressure: 3.48E-06mmHg at 25°C
• Refractive Index: 1.622
• CAS DataBase Reference: 9-TRIFLUOROACETYLANTHRACENE(CAS DataBase Reference)
• NIST Chemistry Reference: 9-TRIFLUOROACETYLANTHRACENE(53531-31-0)
• EPA Substance Registry System: 9-TRIFLUOROACETYLANTHRACENE(53531-31-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 53531-31-0(Hazardous Substances Data)

Usage

Chemical Properties

Yellow powder

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 313, 1979 DOI: 10.1021/jo01316a041Tetrahedron Letters, 36, p. 9117, 1995 DOI: 10.1016/0040-4039(95)01978-Q

InChI:InChI=1/C16H9F3O/c17-16(18,19)15(20)14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-9H

Upstream product

• 120-12-7 anthracene 
• 68602-57-3 trifluoroacetyl triflate 
• 383-63-1 ethyl trifluoroacetate, 
• 1564-64-3 9-Bromoanthracene 
• 407-25-0 trifluoroacetic anhydride 
• 60686-64-8 1-(9-anthryl)-2,2,2-trifluoroethanol 

Downstream Products

• 60646-30-2 (S)-2,2,2-trifluro-1-(anthryl)ethanol 
• 53531-34-3 (R)-2,2,2-trifluoro-1-(9-anthryl)ethanol 

Relevant articles and documents

Method for expedient synthesis of [18F]-labeled α-trifluoromethyl ketones

The present invention is directed to a convenient method of synthesizing radiolabeled α-trifluoromethyl ketones by a fluorination reaction. The present invention also relates to imaging agents and markers for identifying cell proliferation, or viral infection. The markers and imaging agents including the radiolabeled α-trifluoromethyl ketones that are prepared by the present method.

A Mild 10-I-4 Iodinane Oxide Oxidant for Primary and Secondary Alcohols

Iodinane oxide 4 midly and rapidly oxidizes primary and secondary alsohols to their corresponding carbonyl products in excellent yield.Oxidations are carried out in CH2Cl2 at room temperature using 1.1 equivalent of oxidant.Other non-hydroxylic organic solvents may also be used.