54286-79-2Relevant articles and documents
Supramolecular Self-Sorting Networks using Hydrogen-Bonding Motifs
Coubrough, Heather M.,van der Lubbe, Stephanie C. C.,Hetherington, Kristina,Minard, Aisling,Pask, Christopher,Howard, Mark J.,Fonseca Guerra, Célia,Wilson, Andrew J.
supporting information, p. 785 - 795 (2019/01/04)
A current objective in supramolecular chemistry is to mimic the transitions between complex self-sorted systems that represent a hallmark of regulatory function in nature. In this work, a self-sorting network, comprising linear hydrogen motifs, was created. Selecting six hydrogen-bonding motifs capable of both high-fidelity and promiscuous molecular recognition gave rise to a complex self-sorting system, which included motifs capable of both narcissistic and social self-sorting. Examination of the interactions between individual components, experimentally and computationally, provided a rationale for the product distribution during each phase of a cascade. This reasoning holds through up to five sequential additions of six building blocks, resulting in the construction of a biomimetic network in which the presence or absence of different components provides multiple unique pathways to distinct self-sorted configurations.
Conformer independent heterodimerisation of linear arrays using three hydrogen bonds
McGhee, Andrea M.,Kilner, Colin,Wilson, Andrew J.
, p. 344 - 346 (2008/09/19)
5-Membered heterocycles are employed to give a conformer independent DDA array of hydrogen bonds, resulting in enhanced binding affinity to a complementary AAD array in comparison to a DDA array employing a 6-membered ring. The Royal Society of Chemistry.
