54423-54-0

Basic information

• Product Name: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate
• Synonyms: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate;2,3,4,6-Tetra-O-benzyl-D-glucose-1-p-nitrobenzoate;2,3,4,6-tetra-O-benzyl-1-O-(4-nitrobenzoyl)hexopyranose;(3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)-methyl)tetrahydro-2H-pyran-2-yl 4-nitrobenzoat;(3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)-methyl)tetrahydro-2H-pyran-2-yl 4-nitrobenz;(3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)-methyl)tetrahydro-2H-pyran-2-yl 4-nitrobenzoate
• CAS NO: 54423-54-0
• Molecular Formula: C₄₁H₃₉NO₉
• Molecular Weight: 689.77
• Mol File: 54423-54-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 793.7 °C at 760 mmHg
• Flash Point: 258 °C
• Appearance: /
• Density: 1.29 g/cm³
• Vapor Pressure: 3.53E-25mmHg at 25°C
• Refractive Index: 1.636
• Storage Temp.: 2-8°C
• CAS DataBase Reference: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate(54423-54-0)
• EPA Substance Registry System: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate(54423-54-0)

Safety Data

• Hazardous Substances Data: 54423-54-0(Hazardous Substances Data)

Usage

General Description

"[3,4,5-Tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-Nitrobenzoate" is a complex chemical compound. Based on the name, one can identify that it contains several functional groups, including phenylmethoxy groups, an oxan ring, and a nitrobenzoate group. The presence of such a wide variety of functionalities indicates that this compound could have potential for a diverse range of chemical reactions, which could include reactions such as esterification, nucleophilic substitution, or electrophilic aromatic substitution, among others. The physical and chemical properties, safety information, analytical methods, and other specific details surrounding this particular compound are not readily available and may need a more in-depth examination.

InChI:InChI=1/C41H39NO9/c43-40(34-21-23-35(24-22-34)42(44)45)51-41-39(49-28-33-19-11-4-12-20-33)38(48-27-32-17-9-3-10-18-32)37(47-26-31-15-7-2-8-16-31)36(50-41)29-46-25-30-13-5-1-6-14-30/h1-24,36-39,41H,25-29H2

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 122-04-3 4-nitro-benzoyl chloride 
• 62-23-7 4-nitro-benzoic acid 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 110316-55-7 (2R,3R,4R,5S,6R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-((Z)-2-iodo-vinyl)-tetrahydro-pyran 
• 67773-43-7 2,3,4,6-tetra-O-benzyl-α/β-D-glucopyranosyl bromide 
• 4196-35-4 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide 
• 81972-19-2 1-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-2-propene 
• 82659-52-7 1-(2,3,4,6-O-tetrabenzyl-α-D-glucopyranosyl)-2-propene 
• 136034-23-6 β-D-Glucopyranosylphenylmethane 
• 136034-24-7 (2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)phenylmethane 
• 158419-81-9 (Methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)phenylmethane 
• 158419-84-2 (Methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)-4-aminophenylmethane 
• 161909-26-8 (2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-4-aminophenylmethane 
• 158419-85-3 (Methyl 2,3,4-tri-O-acetyl-β-D-glucopyranosyluronate)-4-retinamidophenylmethane 
• 158419-80-8 (2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosyl)-4-retinamidophenylmethane 
• 155590-31-1 (2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl)phenylmethane 
• 100644-74-4 1,3,4,6-tetra-O-acetyl-2-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-α-D-glucopyranose 

Relevant articles and documents

DPPE: A convenient replacement for triphenylphosphine in the Staudinger and Mitsunobu reactions

DPPE has been shown to replace triphenylphosphine in the Staudinger and Mitsunobu reactions. The resulting bis(phosphine oxide) by-product is readily removed allowing for rapid and simple purification of the reaction mixture.

Synthesis of Chiral Spiroacetals from Carbohydrates

Optically active spiroacetals are prepared from carbohydrates with an intramolecular hydrogen abstraction reaction as the key step.Both spiroacetal enantiomers are formally available from the same sugar.