5447-64-3Relevant articles and documents
THE FACILE ADDITION OF FLUOROSULFURIC ACID TO AN EPOXIDE
Poorker, Carol S.,Kagan, Jacques
, p. 6405 - 6408 (1985)
Fluorosulfuric acid, a very poor nucleophile, was found to add to several epoxides, yielding 1,3,2-dioxathiolane 2,2-dioxides.These cyclic sulfates could also be obtained by reacting the epoxides with sulfur trioxide.The intermediacy of the fluorosulfate of a 1,2-diol, which readily cyclized in base, has been demonstrated in one case.
A model for the enzyme-catalyzed, coenzyme B12-dependent interconversion of β-methylaspartate with glutamate
Dowd,Choi,Duah,Kaufman
, p. 2137 - 2148 (2007/10/02)
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