54615-66-6

Basic information

• Product Name: Benzeneacetonitrile, 4-chloro-a-(phenylimino)-
• CAS NO: 54615-66-6
• Molecular Formula: C14H9ClN2
• Molecular Weight: 240.692
• Mol File: 54615-66-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzeneacetonitrile, 4-chloro-a-(phenylimino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetonitrile, 4-chloro-a-(phenylimino)-(54615-66-6)
• EPA Substance Registry System: Benzeneacetonitrile, 4-chloro-a-(phenylimino)-(54615-66-6)

Safety Data

• Hazardous Substances Data: 54615-66-6(Hazardous Substances Data)

Upstream product

• 32377-36-9 anilino(4-chlorophenyl)acetonitrile 
• 104-88-1 4-chlorobenzaldehyde 
• 62-53-3 aniline 
• 5909-74-0 N-phenyl-C-(4-chlorophenyl)nitrone 
• 74225-36-8 C₁₇H₁₉ClN₂OSi 
• 67-56-1 methanol 
• 7541-13-1 anti(phenyl)-N-Fluorimino-(4-chlor-phenyl)-acetonitril 

Downstream Products

• 21854-87-5 N,N'-diphenyl-1,2-di(p-chlorophenyl)ethane-1,2-diimine 
• 3457-46-3 4,4'-dichlorobenzil 

Relevant articles and documents

Synthesis and pharmacological activities of arylarylamino- and aryl-aryliminoacetonitriles

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Reactions of Trimethylsilyl Cyanide and N-(Trimethylsilyl)diphenylmethyleneamine with Nitrones and Thermal Decompositions of Their Adducts

Trimethylsilyl cyanide (1) and N-(trimethylsilyl)diphenylmethyleneamine (2) reacted with α-aryl-N-phenylnitrones to afford the corresponding 1:1 adducts 4 and 5 respectively.Thermal decomposition of 4 in refluxing xylene gave azoxybenzene, stereoisomers of 2,3-diarylsuccinonitriles, α-aminonitriles and/or benzanilides, whose yields depended on the nature of substituents on phenyl group of 4.On heating in benzene 5 afforded a mixture of azoxybenzene and meso-N,N'-bis(diphenylmethylene)-1,2-diarylethylenediamines.On the other hand, reactions of 1 and 2 with N-(diphenylmethylene)aniline N-oxide or N-(9-fluorenylidene)aniline N-oxide did not give the corresponding 1:1 adducts, but instead compounds arising from thermal decomposition of initial 1:1 adducts were directly obtained.The reaction of 1 with N-(p-diethylaminophenyl)-α-phenylnitrone leading to the corresponding α-imino nitrile is also described.