547-15-9Relevant articles and documents
First total synthesis and assignment of the stereochemistry of crispatenine
Bourdron, Julien,Commeiras, Laurent,Audran, Gerard,Vanthuyne, Nicolas,Hubaud,Parrain, Jean-Luc
, p. 3770 - 3775 (2008/02/04)
(Figure Presented) The first racemic and enantioselective synthesis of crispatenine 1 has been achieved, which involved a few steps, enabling the assignment of the absolute and relative configurations.
Stereoselective Synthesis of (+/-)-Ancistrofuran and its Stereoisomers
Baker, Raymond,Cottrell, Ian F.,Ravenscroft, Paul D.,Swain, Christopher J.
, p. 2463 - 2468 (2007/10/02)
The four possible stereoisomers of ancistrofuran have been prepared from γ-cyclohomocitral.Addition of 3-furyl-lithium yielded two epimeric alcohols.Each alcohol was epoxidised with m-chloroperbenzoic acid and reduction with lithium aluminium hydride gave
Sulphone-based Elimination Reactions in Synthesis. Part 2. Diumycinol
Kocienski, Philip,Todd, Michael
, p. 1783 - 1789 (2007/10/02)
Diumycinol , a hydrolytic product of the antibiotic diumycin, was assembled from three fragments: 1-(2-phenylsulphonylethyl)-2-methylene-6,6-dimethylcyc