54758-36-0

Basic information

• Product Name: Benzene, (1-methyl-1,3-butadienyl)-
• CAS NO: 54758-36-0
• Molecular Formula: C11H12
• Molecular Weight: 144.216
• Mol File: 54758-36-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, (1-methyl-1,3-butadienyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-methyl-1,3-butadienyl)-(54758-36-0)
• EPA Substance Registry System: Benzene, (1-methyl-1,3-butadienyl)-(54758-36-0)

Safety Data

• Hazardous Substances Data: 54758-36-0(Hazardous Substances Data)

Upstream product

• 52741-30-7 (1-methyl-1,2-butadienyl)benzene 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 723340-75-8 (2R,3E)-4-phenylpent-3-en-2-ol acetate 
• 18925-10-5 allylzinc bromide 
• 98-86-2 acetophenone 
• 1730-25-2 allylmagnesium bromide 
• 2741-38-0 allyldiphenylphosphine 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 2719-52-0 2-phenylpentane 
• 1276069-52-3 C₁₃H₁₆O₂ 
• 1449569-13-4 (E)-2,2-(4-phenylpenta-1,3-diene-1,1-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane) 
• 1449569-01-0 4,4,5,5-tetramethyl-2-(4-phenylpenta-1,3-dien-1-yl)-1,3,2-dioxaborolane 
• 1449569-02-1 4,4,5,5-tetramethyl-2-(4-phenylpenta-1,3-dien-1-yl)-1,3,2-dioxaborolane 

Relevant articles and documents

Catalytic formal [4 + 2] cycloadditions between unactivated allenes and N-hydroxyaniline catalyzed by AuCl3/CuCl2/O2

AuCl3-catalyzed formal [4 + 2]-cycloadditions between substituted allenes and N-hydroxyanilines are described. This reaction sequence comprises initial isomerizations of allenes to butadienes under N2 and subsequent oxidations of N-h

A novel ketone olefination via organozinc reagents in the presence of diphenyl phosphite

Carbonyl compounds react with organozinc reagents in the presence of diphenyl phosphite to give the corresponding olefins. A variety of 1,3-dienes and unsaturated esters were obtained in moderate to excellent yields under mild conditions. The Royal Society of Chemistry 2012.

An efficient and highly selective deprotecting method for β-(trimethylsilyl)ethoxymethyl ethers

A series of β-(trimethylsilyl)ethoxymethyl ethers were hydrolyzed to their corresponding alcohols in high yields by using a catalytic amount of CBr4 (15%) in MeOH under refluxing reaction conditions. The chemoselective deprotection between trialkylsilyl and β-(trimethylsilyl)-ethoxymethyl-protected alcohols can be achieved by using an alcohol with steric hindrance such as iPrOH. The selectivity also can be achieved in the CBr4/MeOH reaction mixture under ultrasonic reaction conditions.