54887-54-6 Usage
Description
ANISOLE-D8 is a deuterated form of anisole, an organic compound that serves as a solvent and is used in the production of perfumes and pharmaceuticals. Also known as methoxybenzene, it consists of a benzene ring with a methoxy group (CH3O) attached. ANISOLE-D8 is specifically labeled with deuterium, a stable isotope of hydrogen, which makes it valuable as a reagent and internal standard in nuclear magnetic resonance (NMR) spectroscopy. Additionally, it is utilized in research and chemical synthesis, where the deuterium labeling offers insights into the molecule's position and behavior during reactions and processes. ANISOLE-D8 is a clear, colorless liquid characterized by a sweet, pleasant odor, and it should be handled with care due to its potential harmful effects if ingested, inhaled, or contacted through the skin.
Uses
Used in NMR Spectroscopy:
ANISOLE-D8 is used as a reagent and internal standard in nuclear magnetic resonance (NMR) spectroscopy for its deuterium labeling, which aids in providing specific information about the position and behavior of the anisole molecule in various reactions and processes.
Used in Research and Chemical Synthesis:
ANISOLE-D8 is employed in research and chemical synthesis as a deuterated compound, allowing for the study of molecular interactions and the tracking of the anisole molecule's behavior during chemical reactions.
Used in the Production of Perfumes and Pharmaceuticals:
ANISOLE-D8 is utilized in the production of perfumes and pharmaceuticals due to its solvent properties and its role in the synthesis of various compounds.
Used as a Solvent:
ANISOLE-D8 is used as a solvent in various chemical processes, taking advantage of its ability to dissolve a wide range of substances and facilitate reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 54887-54-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,4,8,8 and 7 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 54887-54:
(7*5)+(6*4)+(5*8)+(4*8)+(3*7)+(2*5)+(1*4)=166
166 % 10 = 6
So 54887-54-6 is a valid CAS Registry Number.
54887-54-6Relevant articles and documents
Heterolytic Oxidative Addition of sp2and sp3C-H Bonds by Metal-Ligand Cooperation with an Electron-Deficient Cyclopentadienone Iridium Complex
Higashi, Takuya,Kusumoto, Shuhei,Nozaki, Kyoko
supporting information, p. 12999 - 13004 (2021/08/16)
Oxidative addition reactions of C-H bonds that generate metal-carbon-bond-containing reactive intermediates have played essential roles in the field of organometallic chemistry. Herein, we prepared a cyclopentadienone iridium(I) complex 1 designed for oxidative C-H bond additions. The complex cleaves the various sp2 and sp3 C-H bonds including those in hexane and methane as inferred from their H/D exchange reactions. The hydroxycyclopentadienyl(nitromethyl)iridium(III) complex 2 was formed when the complex was treated with nitromethane, which highlights this elementary metal-ligand cooperative C-H bond oxidative addition reaction. Mechanistic investigations suggested the C-H bond cleavage is mediated by polar functional groups in substrates or another iridium complex. We found that ligands that are more electron-deficient lead to more favorable reactions, in sharp contrast to classical metal-centered oxidative additions. This trend is in good agreement with the proposed mechanism, in which C-H bond cleavage is accompanied by two-electron transfer from the metal center to the cyclopentadienone ligand. The complex was further applied to catalytic transfer-dehydrogenation of tetrahydrofuran (THF).
