549520-99-2Relevant articles and documents
New chiral π-conjugated polymers based on a (1R,2R)-diiminocyclohexane chiral unit with weak interchain π stacking
Lere-Porte, Jean-Pierre,Moreau, Joel J. E.,Serein-Spirau, Francoise,Wakim, Salem
, p. 3020 - 3021 (2002)
New chiral π-conjugated polymers consisting of alternating conjugated segments and (1R,2R)-diiminocyclohexane units with C2 symmetry were prepared by a palladium-catalyzed coupling reaction, they exhibited very high specific optical rotations ([α] up to -3000°) and strong Cotton effects ([θ] 106 deg cm2 mol-1).
An easy and clean synthesis of chiral 3,4-diaryl-2,5-diazabicyclo[4.4.0]decanes by reductive intramolecular coupling of chiral diimines
Hesemann, Peter,Moreau, Joel J. E.,Soto, Thierry
, p. 183 - 189 (2007/10/03)
A clean and efficient reductive intramolecular coupling of diimines prepared from (1R,2R)-cyclohexanediamine gave chiral 2,3-diarylpiperazines.