55108-47-9Relevant articles and documents
REACTION OF CESIUM PERFLUOROALKOXIDES WITH HEXAFLUOROPROPYLENE OXIDE IN TETRAHYDROFURAN IN THE PRESENCE OF ADDITIONS OF APROTIC SOLVENTS
Gubanov, V. A.,Tyul'ga, G. M.,Solodkaya, I. G.,Sherman, M. A.
, p. 444 - 448 (2007/10/02)
The effect of adition of aprotic solvents in tetrahydrofuran on the reactivity of cesium perfluoroalkoxides with hexafluoropropylene oxide was investigated.It was shown that the rate of the model chain transfer to the monomer increases with increase in the concentration of tetraglyme in proportion to the increase in the electric conductivity of the system.The reactivity of cesium perfluoroalkoxides is determined by the structure of the perfluorinated radical.A mechanism is proposed for the chain growth and transfer reaction.