55382-49-5

Basic information

• Product Name: 5-chloro-2-methoxy-1,1'-biphenyl
• Synonyms: 5-chloro-2-methoxy-1,1'-biphenyl
• CAS NO: 55382-49-5
• Molecular Weight: 218.683
• Mol File: 55382-49-5.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 5-chloro-2-methoxy-1,1'-biphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 5-chloro-2-methoxy-1,1'-biphenyl(55382-49-5)
• EPA Substance Registry System: 5-chloro-2-methoxy-1,1'-biphenyl(55382-49-5)

Safety Data

• Hazardous Substances Data: 55382-49-5(Hazardous Substances Data)

Upstream product

• 623-12-1 4-chloromethoxybenzene 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 696-62-8 para-iodoanisole 
• 71-43-2 benzene 
• 553-82-2 1,3-dichloro-4-methoxybenzene 
• 591-50-4 iodobenzene 
• 60633-25-2 2-bromo-4-chloroanisole 
• 98-80-6 phenylboronic acid 
• 90-43-7 2-Phenylphenol 
• 19434-42-5 4-amino-6-phenylphenol 
• 607-12-5 5-chloro-biphenyl-2-ol 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 607-12-5 5-chloro-biphenyl-2-ol 

Relevant articles and documents

Search for a photoinduced (site-selective) cleavage of the Ar-Cl bond in dichloroanisoles

The site-selective cleavage of an Ar-X bond in polyhalogenated aromatics is an important tool in synthetic planning especially when more than one identical halogen atom is present. An alternative to the usual metal-catalyzed cleavage is represented by photochemistry although only a few examples have been reported. We then investigated the feasibility of the site-selective photodechlorination of some dichloroanisoles through a combined experimental and computational study. In the case of 2,4-dichloroanisole, selective detachment of the chlorine atom at the ortho position with respect to the OMe group was observed upon photohomolysis (in cyclohexane) or photoheterolysis (in MeOH) of the Ar-Cl bond. In the latter case, 5-chloro-2-methoxy-1,1′-biphenyl was exclusively formed upon reaction of the resulting phenyl cation with benzene. The substitution of an OH group for a OMe group was detrimental since a lower photoreactivity resulted with no improvement in the selectivity.

Condensed-cyclic compound and organic light emitting diode comprising the same

Disclosed are a condensed-ring compound and an organic light-emitting device comprising the same. The condensed-ring compound is represented by chemical formula 1. The organic light-emitting device comprising the condensed-ring compound can have low driving voltage, high efficiency, high brightness, and long durability.COPYRIGHT KIPO 2016

The 1,3-diaminobenzene-derived aminophosphine palladium pincer complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A highly active Suzuki-Miyaura catalyst with excellent functional group tolerance

The rapidly prepared 1,3-diaminobenzenederived aminophosphine pincer complex {C6H3 [NHP(piperidinyl)2] 2Pd(Cl)} (1) is an effective Suzuki catalyst with excellent functional group tolerance. Side-product formations, such as homocoupling, debromation or protodeboration have only rarely been detected and if so, were in all cases below the 5% level. The presented reaction protocol is universally applicable. Experimental observations indicate that palladium nanoparticles are the catalytically active form of 1.