557-39-1

Basic information

• Product Name: MAGNESIUM FORMATE 0.2 M SOLUTION*
• Synonyms: formatedemagnesium;MAGNESIUM FORMATE 0.2 M SOLUTION*;magnesium diformate;MAGNESIUM FORMATE SOLUTION 1M;Magnesiumformiat-2-hydrat;Bisformic acid magnesium salt;Diformic acid magnesium salt;Einecs 209-173-9
• CAS NO: 557-39-1
• Molecular Formula: 2CHO₂*Mg
• Molecular Weight: 114.33988
• EINECS: 209-173-9
• Product Categories: MOFs;Alternative Energy;Catalysis and Inorganic Chemistry;Chemical Synthesis;Materials Science;Metal Organic Frameworks (MOFs)
• Mol File: 557-39-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 100.6 °C at 760 mmHg
• Flash Point: 29.9 °C
• Appearance: /
• Density: 1.038 g/mL at 20 °C
• Storage Temp.: 2-8°C
• Solubility: H2O: 0.5 M, clear, colorless
• CAS DataBase Reference: MAGNESIUM FORMATE 0.2 M SOLUTION*(CAS DataBase Reference)
• NIST Chemistry Reference: MAGNESIUM FORMATE 0.2 M SOLUTION*(557-39-1)
• EPA Substance Registry System: MAGNESIUM FORMATE 0.2 M SOLUTION*(557-39-1)

Safety Data

• Safety Statements: 23-24/25
• WGK Germany: 3
• Hazardous Substances Data: 557-39-1(Hazardous Substances Data)

Usage

General Description

This product has been enhanced for energy efficiency.

InChI:InChI=1/CH2O2.Mg/c2-1-3;/h1H,(H,2,3);/q;+2/p-1

Upstream product

• 141-53-7 sodium formate 
• 7786-30-3 magnesium chloride 
• 6150-82-9 magnesium(II) formate dihydrate 
• 142-72-3 magnesium acetate 
• 201230-82-2 carbon monoxide 
• 107-31-3 Methyl formate 
• 64-18-6 formic acid 

Downstream Products

• 547-66-0 magnesium(II) oxalate 
• 67-56-1 methanol 
• 124-38-9 carbon dioxide 
• 201230-82-2 carbon monoxide 
• 7440-44-0 pyrographite 
• 64-18-6 formic acid 
• 107-31-3 Methyl formate 

Relevant articles and documents

PROCESS FOR PREPARING A METAL-ORGANIC FRAMEWORK

The present invention relates to a process for preparing a magnesium formate based metal-organic framework. The process comprises (a) combining magnesium or magnesium oxide with formic acid; (b) heating the reaction mixture of step (a) at a temperature of between 70°C and 200°C; (c) combining formic acid with the reaction mixture of step (b); and (d) heating the reaction mixture of step (c) at a temperature of between 70°C and 200°C. Steps (c) and (d) may be heated up to 5 times.

CO2-"Neutral" hydrogen storage based on bicarbonates and formates

Let the circle be unbroken! One ruthenium catalyst generated in situ facilitates the selective hydrogenation of bicarbonates and carbonates, as well as CO2 and base, to give formates and also the selective dehydrogenation of formates back to bicarbonates. The two reactions can be coupled, leading to a reversible hydrogen-storage system. dppm=1,2- bis(diphenylphosphino)methane. Copyright

Measurement of equilibrium water vapor pressures for the thermal dehydrations of some formate dihydrates by means of the transpiration method

The equilibrium water vapor pressures, PH2O for the thermal dehydrations of some formate dihydrates, M(HCO2)2·2H2O, where M is Mg, Mn, Co, Ni and Zn, were measured by means of the transpiration method using a laboratory-made apparatus. These hydrates have a monoclinic isomorphous crystal structure with a space group, P21/C. The thermodynamic data such as ΔG, ΔH and ΔS for the dehydration were derived from the PH2O and correlated to the crystal structures of these hydrates. Although the values of ΔH were expected to increase in the order of the hydrates of Mn2+-OH2 bond, they increased in the order of Mn2)2·2H2O and Zn(HCO2)2·2H2O seemed to be due to the relatively strong hydrogen bond between the water molecules and the formate ions. The values of ΔG obtained at 373 K, ΔG(373) showed a good correlation with the beginning temperatures of the dehydrations, Ti.