5573-37-5

Basic information

• Product Name: (C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2
• Synonyms: (C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2
• CAS NO: 5573-37-5
• Molecular Weight: 341.412
• Mol File: 5573-37-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: (C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2(5573-37-5)
• EPA Substance Registry System: (C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2(5573-37-5)

Safety Data

• Hazardous Substances Data: 5573-37-5(Hazardous Substances Data)

Upstream product

• 2040-00-8 diethylaluminum iodide 
• 41979-47-9 N-tert-butyl-1,1-diphenylphosphinamine 

Downstream Products

• 86480-66-2 (CO)3MnHCH₂Al(CH₃)N(C(CH₃)3)P(C₆H₅)2CHO(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2 
• 83632-49-9 (CO)3MnHCH(CH₃)Al(C₂H₅)N(C(CH₃)3)P(C₆H₅)2CHO(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2 
• 83649-33-6 (CO)3Mn(P(OC₆H₅)3)(OCH(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2) 
• 86480-65-1 (CO)4Mn(OC(⁽²⁾H)(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2) 
• 83585-44-8 C₅H₅Fe(OCHCH₂)COAl(C₂H₅)2NC(CH₃)3P(C₆H₅)2 
• 83585-43-7 C₅H₅Fe(COCH₃)COAl(C₂H₅)2NC(CH₃)3P(C₆H₅)2 
• 83585-42-6 (CO)(C₅H₅)Fe(OC(CH₃)(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2) 
• 84836-35-1 (C₅H₅)(CO)Fe(C(C₆H₅)OAl(C₂H₅)2NC(CH₃)3P(C₆H₅)2) 
• 83632-48-8 (CO)4Mn(OCH(C₆H₅)2PN(C(CH₃)3)Al(C₂H₅)2) 
• 84824-75-9 [CH₃P(C₆H₅)2NC(CH₃)3Al(C₂H₅)2]⁽¹⁺⁾*I^(1-)=[CH₃P(C₆H₅)2NC(CH₃)3Al(C₂H₅)2]I 

Relevant articles and documents

Amphoteric ligands. 3. Reactions of alkylmetal carbonyls with (aluminoamino)phosphine ligands. Structure of (η-C5H5)(CO)Fe(C(CH3)OAl(C 2H5)2N(C(CH3)3)P(C 6H5)2)

Amphoteric ligands Ph2PNRAlR′2 react with alkylmetal carbonyl complexes to induce facile migrations. The reaction of Ph2PN-t-BuAlEt2 with CpFe(CO)2Me (Cp = η5-C5H5) gives as major product the chelated acyl complex Cp(CO)Fe(C(Me)OAlEt2N-t-BuPPh2), along with smaller amounts of Cp(CO)Fe(O-(CH=CH2)AlEt2N-t-BuPPh2). An intermediate leading to these products was characterized crystallographically as Cp(CO)Fe(C(Me)OAlEt2N-t-BuPPh2). Crystal data: triclinic; space group P1; a = 10.474 (2) A?, b = 15.677 (3) A?, c = 9.707 (1) A?; α = 97.98 (1)°, β = 115.01 (1)°, γ = 71.81 (1)°; Z = 2; final R = 0.049 for 4303 reflections used. The molecule consists of a five-membered heterocycle, C(Me)OAl-(Et)2N(t-Bu)P(Ph)2, bonded in η2(C, O) fashion to a Cp(CO)Fe fragment, with Fe-C = 1.983 (3) A?, Fe-O = 1.969 (2) A?, and C-O = 1.401 (3) A?.