559-40-0Relevant articles and documents
Preparation method of octafluorocyclopentene
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Paragraph 0029; 0031-0032; 0034-0035; 0037, (2021/04/14)
The invention relates to a preparation method of octafluorocyclopentene, and belongs to the technical field of chemical engineering. The method comprises the following steps: (1) dissolving 1, 2-dichlorocyclopentane in carbon tetrachloride, cooling to 0-20 DEG C, introducing diluted fluorine gas, stirring, heating to 30-50 DEG C, carrying out fluorination and fluorination reaction for 1-2 hours to obtain a product, and separating and purifying to obtain 1, 2-dichlorooctafluorocyclopentane; and (2) dissolving a reductive dechlorination reagent in a dry polar solvent, stirring, protecting by protective gas, heating to 50-80 DEG C, dropwise adding the 1, 2dichlorooctafluorocyclopentane by adopting a constant-pressure dropping funnel, continuously reacting for 0.5-1.5 hours when no foam is generated, and collecting the generated gas by using a cold trap. The method is simple to operate; high-temperature and high-pressure conditions are not set, and reaction conditions are mild; and less three wastes are generated, the environmental pressure is low, and the method belongs to a green synthesis process.
Preparation method of halogenation cycloolefin
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Paragraph 0064; 0065, (2019/08/20)
The invention relates to a preparation method of halogenation cycloolefin and belongs to the field of chemical synthesis. According to the preparation method, in an amide or alkylamine solvent, with halogenation cycloparaffin as a raw material, a dehalogenation reaction is conducted, and the target product halogenation cycloolefin is obtained. According to the method, the reaction conditions are mild, the yield of the halogenation cycloolefin is high, dangerous reduction agents such as metal or hydrogen do not need to be used, the technology is safe and reliable, solid waste such as metal halide is not generated, and a common distillation means can be used for effective industrial separation.
Industrial production method for perfluorocyclopentene
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, (2018/07/07)
The invention discloses an industrial production method for perfluorocyclopentene, and belongs to the field of fine chemical intermediate synthesis. Cyclopentene, chlorine and pyridine hydrofluoride which are used as raw materials undergo high-temperature chlorination in a solvent sulfolane to obtain octachlorocyclopentene, and the octachlorocyclopentene and pyridine hydrofluoride undergo high-temperature fluorination substitution to obtain the perfluorocyclopentene. Residues obtained after the separation of the product undergo reduced pressure distillation to obtain the solvent sulfolane which can be reused. The method allows the product yield to reach 45-55%, the product content to be more than 99%, the water content to be less than 0.1% and the chloride ion content to be less than 0.1%. The method has the advantages of no pollution in the production process, green production process, high yield, simple steps, facilitation of the reduction of the production cost, high product purity, and facilitation of later application.