56231-51-7

Basic information

• Product Name: 3-(3-methoxyphenyl)cyclohex-2-en-1-one
• Synonyms: 3-(3-methoxyphenyl)cyclohex-2-en-1-one
• CAS NO: 56231-51-7
• Molecular Weight: 202.253
• Mol File: 56231-51-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: 3-(3-methoxyphenyl)cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-methoxyphenyl)cyclohex-2-en-1-one(56231-51-7)
• EPA Substance Registry System: 3-(3-methoxyphenyl)cyclohex-2-en-1-one(56231-51-7)

Safety Data

• Hazardous Substances Data: 56231-51-7(Hazardous Substances Data)

Upstream product

• 10365-98-7 3-methoxyphenylboronic acid 
• 504-02-9 1,3-cylohexanedione 
• 56671-81-9 3-bromo-2-cyclohexen-1-one 
• 23074-59-1 3-isobutoxycyclohex-2-en-1-one 
• 36282-40-3 (3-methoxyphenyl)magnesium bromide 
• 930-68-7 cyclohexenone 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 100-66-3 methoxybenzene 
• 15321-51-4 diiron nonacarbonyl 
• 1884-41-9 1-Cyclohex-1-enyl-3-methoxy-benzene 
• 598-32-3 2-hydroxy-3-butene 
• 586-37-8 1-(3-Methoxyphenyl)ethanone 

Downstream Products

• 79881-58-6 3-(m-Methoxyphenyl)-2-cyclohexen-1-ol 
• 1010820-97-9 trifluoromethanesulfonic acid 3-allyl-3-(3-methoxyphenyl)cyclohex-1-enyl ester 
• 1613527-27-7 N-(3-(3-methoxyphenyl)cyclohex-2-enyl)acetamide 
• 1613527-47-1 N-(5-(3-methoxyphenyl)cyclohexa-1,5-dienyl)acetamide 
• 1186225-51-3 (R)-3-(3-methoxyphenyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohexan-1-one 
• 1601389-60-9 (S)-3-(3-methoxyphenyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohexan-1-one 
• 56231-52-8 3-(3-methoxyphenyl)-3-cyano-cyclohexanone 
• 56231-53-9 methyl 1-(3-methoxyphenyl)-3-oxo-cyclohexane-1-carboxylate 
• 86446-33-5 <1-(m-methoxyphenyl)-2-cyclohexen-1-yl>acetic acid, ethyl ester 
• 86446-17-5 <1-(m-methoxyphenyl)-2-cyclohexen-1-yl>acetic acid, dimethylamide 
• 86446-11-9 <1-(m-methoxyphenyl)-2-cyclohexen-1-yl>acetic acid 

Relevant articles and documents

Palladium mediated one-pot synthesis of 3-aryl-cyclohexenones and 1,5-diketones from allyl alcohols and aryl ketones

One-pot synthesis of Robinson annulated 3-aryl-cyclohexenones from allyl alcohols and ketones using palladium is reported. Long chain aliphatic or aryl substitutions at the C1 position of allyl alcohol result in the formation of 1,5-diketone products. This simple one-pot method avoids the use of highly electrophilic vinyl ketones.

An Electrophilic Trifluoromethylthiolation of Silylenol Ethers and β-Naphthols with Diethylaminosulfur Trifluoride and (Trifluoromethyl)trimethylsilane

An efficient and general trifluoromethylthiolation of silylenol ethers and β-naphthols have been accomplished employing the combination of diethylaminosulfur trifluoride (DAST) and (trifluoromethyl)trimethylsilane (CF3TMS) as source of electrophilic trifluoromethylthio moiety for the synthesis of α-trifluoromethylthiolated carbonyl compounds and β-naphthols in good yields. Important features of this method include wide functional group tolerance and use of readily available DAST/CF3TMS. Potential of the methodology was demonstrated via the synthesis of α-trifluoromethylthiolated (+)-4-cholesten-3-one and naphthoquinone. (Figure presented.).

Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α, β-cyclohexenones

A Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to α, β-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the α-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)5-mediated [5+1] reaction, the use of cheap and safe Fe2(CO)9 and abandoning the photo-irradiation conditions are the two major advantages of the present method.