5633-57-8

Basic information

• Product Name: Benzene,1-methoxy-4-(phenylthio)-
• Synonyms: Benzene,1-methoxy-4-(phenylthio)-
• CAS NO: 5633-57-8
• Molecular Formula: C₁₃H₁₂OS
• Molecular Weight: 216.3
• Mol File: 5633-57-8.mol
• Article Data: 291

Chemical Properties

• Boiling Point: 350.7°Cat760mmHg
• Flash Point: 165.9°C
• Appearance: /
• Density: 1.15g/cm³
• Vapor Pressure: 8.73E-05mmHg at 25°C
• Refractive Index: 1.622
• CAS DataBase Reference: Benzene,1-methoxy-4-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene,1-methoxy-4-(phenylthio)-(5633-57-8)
• EPA Substance Registry System: Benzene,1-methoxy-4-(phenylthio)-(5633-57-8)

Safety Data

• Hazardous Substances Data: 5633-57-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12OS/c1-14-11-7-9-13(10-8-11)15-12-5-3-2-4-6-12/h2-10H,1H3

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 1192-40-1 copper(I) thiophenolate 
• 623-12-1 4-chloromethoxybenzene 
• 696-62-8 para-iodoanisole 
• 930-69-8 sodium thiophenolate 
• 17333-79-8 p-methoxybenzenediazonium 
• 108-98-5 thiophenol 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 931-59-9 benzenesulfenyl chloride 
• 5633-55-6 4-phenylsulfanylphenol 
• 77-78-1 dimethyl sulfate 
• 74-88-4 methyl iodide 
• 17314-33-9 tributyltin phenyl sulfide 
• 591-50-4 iodobenzene 

Downstream Products

• 5633-55-6 4-phenylsulfanylphenol 
• 3112-84-3 4-methoxyphenyl phenyl sulfone 
• 951-92-8 1-methoxyl-4-(phenylsulfinyl)benzene 
• 882-33-7 diphenyldisulfane 
• 127279-74-7 (4-methoxyphenyl)diphenylsulfonium hexafluoroantimonate 
• 53279-48-4 C₁₄H₁₃ClOS 
• 106-41-2 4-bromo-phenol 
• 74-88-4 methyl iodide 
• 7402-69-9 p-hydroxyphenyl p-tolyl sulfone 
• 931-59-9 benzenesulfenyl chloride 
• 53279-49-5 [4-(4-Methoxy-phenylsulfanyl)-phenyl]-acetonitrile 
• 53279-51-9 4-[[4-(2-aminoethyl)phenyl]thio]phenol 
• 53279-50-8 2-[4-[(4-methoxyphenyl)thio]phenyl]ethylamine 
• 97361-14-3 1-(4-((4-methoxyphenyl)thio)phenyl)ethan-1-one 

Relevant articles and documents

Evidence for a mono-electron transfer process in the BF3-promoted reaction of 4'-nitrobenzenesulphenanilide (NBSA)

ESR spectroscopy shows the formation of a radical species in the BF3-promoted reaction of NBSA, an acid/base Lewis-type reaction.

Environmentally Friendly and Recyclable CuCl 2-Mediated C-S Bond Coupling Strategy Using DMEDA as Ligand, Base, and Solvent

Simple reaction conditions and recyclable reagents are crucial for environmentally friendly industrial applications. An environment-friendly, recyclable and economic strategy was developed to synthesize diaryl chalcogenides by the CuCl2-catalyzed C S bondformation reaction via iodobenzenes and benzenethiols/1,2-diphenyldisulfanes using N,N'-dimethylethane-1,2-diamine (DMEDA) as ligand, base, and solvent. For these reactions, especially the reactions of diiodobenzenes and aminobenzenethiols/disulfanediyldianilines, a range of substrates are compatible and give the corresponding products in good to excellent yields. Both of the reagents in the catalytic system (CuCl2/DMEDA) are inexpensive, conveniently separable, and recyclable for more than five cycles.

Engaging Ag(0) single atoms in silver(I) salts-mediated C-B and C-S coupling under visible light irradiation

Silver(I) salts were found active in the borylation and sulfenylation of aryl iodides under visible light irradiation. The optimized borylation protocol using AgF did not need any additive, operated under very mild conditions, and well tolerated a broad scope of substrates and boron sources. Formation of Ag(0) single atoms (AgSAs) during the borylation reactions was examined using high-angle annular dark field aberration-corrected scanning transmission electron microscope (HAADF AC-STEM) and electron paramagnetic resonance (EPR). The activities of the silver(I) salts were affected by the anions and could be associated with their abilities in formation of AgSAs during the reactions. Kinetic studies showed that the deiodination rate was linearly correlated with the loading of AgSAs, and hence AgSAs were the true catalytic centers for the 1e?-reduction of the C-I moieties. The oxidation state of AgSAs kept 0 in both the resting and the working states. A “work-in-tandem” mechanism involving AgSAs as the catalytic centers and AgNPs as the light absorber to achieve the borylation of aryl iodides under visible light irradiation is proposed. The current approach not only provides an alternative system for borylation and sulfenylation of aryl iodides, but also reveals a new activity of silver(I) salts involving AgSAs under visible light irradiation.