564456-59-3Relevant articles and documents
Fluorescent material with piezochromism and slovatochromism and preparation method thereof
-
Paragraph 0062-0065; 0083; 0084; 0104; 0105; 0125; 0126, (2021/05/12)
The invention relates to a fluorescent material with piezochromism and slovatochromism and a preparation method thereof, and belongs to the technical field of fluorescent materials. The fluorescent material with the piezochromism and the slovatochromism comprises a cyano-substituted p-phenylenevinylene compound, and the structural formula of the cyano-substituted p-phenylenevinylene compound is shown in the specification. The invention further discloses a preparation method of the fluorescent material with the piezochromism and the slovatochromism. The fluorescent material has slovatochromism and piezo-chromism performance at the same time, and compared with an existing fluorescent material, the application range is wider, and popularization is facilitated.
Bipyridyl ligand and preparation method thereof, ruthenium supramolecular self-assembly body containing bipyridyl ligand and preparation method and application of ruthenium supramolecular self-assembly
-
Paragraph 0030-0036, (2020/08/18)
The invention provides a novel bipyridyl bidentate ligand and a preparation method thereof. The structural formula of the novel bipyridyl bidentate ligand is shown in the specification. The inventionfurther provides a ruthenium supramolecular self-assembly body of the ligand and a preparation method of the ruthenium supramolecular self-assembly body. The preparation method comprises the followingsteps: putting a prepared ruthenium receptor and a bipyridyl ligand into a container, adding a mixed solvent of methanol and dichloromethane in equal proportion, stirring for a period of time at roomtemperature, spin-drying the solution to a certain volume after the reaction is finished, slowly adding diethyl ether, and separating out solid powder, namely the ruthenium supramolecular self-assembly body containing the bipyridyl ligand. The self-assembly body is a novel ruthenium-containing self-assembly compound, and has a good inhibition effect on cancer tumor cell lines A549 and HepG-2.
Merging strong and weak coordination motifs in the integrative self-sorting of a 5-component trapezoid and scalene triangle
Saha, Manik Lal,Bats, Jan W.,Schmittel, Michael
supporting information, p. 5592 - 5595 (2013/09/12)
In a dynamic six-component library, the formation of the rather weak HETPYP-I complexation can be enforced by exploiting the orthogonality and high stability of its counterpart in the sorting process, a HETTAP complex. The concept was used in a follow-up integrative self-sorting, enabling the formation of two five-component supramolecular structures: a trapezoid and a scalene triangle.