565184-85-2

Basic information

• Product Name: 1,1-Cyclohexanedicarboxylic acid, 2-(1,3-benzodioxol-5-ylmethylene)-3-methylene-, dimethyl ester, (2E)-
• CAS NO: 565184-85-2
• Molecular Formula: C19H20O6
• Molecular Weight: 344.364
• Mol File: 565184-85-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,1-Cyclohexanedicarboxylic acid, 2-(1,3-benzodioxol-5-ylmethylene)-3-methylene-, dimethyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-Cyclohexanedicarboxylic acid, 2-(1,3-benzodioxol-5-ylmethylene)-3-methylene-, dimethyl ester, (2E)-(565184-85-2)
• EPA Substance Registry System: 1,1-Cyclohexanedicarboxylic acid, 2-(1,3-benzodioxol-5-ylmethylene)-3-methylene-, dimethyl ester, (2E)-(565184-85-2)

Safety Data

• Hazardous Substances Data: 565184-85-2(Hazardous Substances Data)

Upstream product

• 849517-53-9 6-iodo-3-methylene-hex-1-yne 
• 110316-91-1 4-methylenehex-5-yn-1-ol 
• 5876-51-7 5-iodo-1,3-benzodioxole 
• 497108-26-6 2-(4-methylene-hex-5-ynyl)malonic acid dimethyl ester 

Relevant articles and documents

New method for the synthesis of functionalized 1,3-bis-exocyclic dienes via a palladium-catalyzed reaction. Scope and synthetic applications

The palladium-catalyzed tandem cyclization-coupling reaction of conjugated enynes having a stabilizing carbon nucleophile with aryl iodides and vinyl halides or triflates produced stereo-defined, functionalized five- and six-membered 1,3-bis-exocyclic dienes in moderate to good yields. These stereodefined dienes proved to be versatile substrates for the preparation of various polycyclic products through subsequent Diels-Alder, intramolecular Friedel-Crafts or thermal electrocyclization reactions.