565214-84-8

Basic information

• Product Name: Silane, [1-ethoxy-2,2,2-trifluoro-1-(trimethylsilyl)ethoxy]trimethyl-
• CAS NO: 565214-84-8
• Molecular Formula: C10H23F3O2Si2
• Molecular Weight: 288.458
• Mol File: 565214-84-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, [1-ethoxy-2,2,2-trifluoro-1-(trimethylsilyl)ethoxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [1-ethoxy-2,2,2-trifluoro-1-(trimethylsilyl)ethoxy]trimethyl-(565214-84-8)
• EPA Substance Registry System: Silane, [1-ethoxy-2,2,2-trifluoro-1-(trimethylsilyl)ethoxy]trimethyl-(565214-84-8)

Safety Data

• Hazardous Substances Data: 565214-84-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 383-63-1 ethyl trifluoroacetate, 

Relevant articles and documents

Non-defluorinative electrochemical silylation of ethyl trifluoroacetate: A practical synthesis of trifluoroacetyltrimethylsilane via its ethyltrimethylsilyl ketal

An efficient method for the preparation of original trifluoroacetyltrimethylsilane, CF3COSiMe3 (3), in two steps from readily available ethyl trifluoroacetate is described. Electrochemical reduction of this ester using a sacrificial anode and performed on a semimolar scale afforded the unprecedented corresponding ketal, CF3C(SiMe3)(OSiMe3)OEt (2) in 30-56% isolated yield. Treated with concentrated sulphuric acid at room temperature, the latter directly led to pure acylsilane 3 in 86% yield.