56757-75-6Relevant articles and documents
Multiblock copolymer synthesis via controlled radical polymerization in aqueous dispersions. Part 1: Synthesis of S-tert-alkyl-N,N- alkoxycarbonylalkyldithiocarbamates
Bussels, Raf,Koning, Cor E.
, p. 1167 - 1174 (2007/10/03)
In a novel two- or three-step synthetic route, S-(1,4-phenylenebis(propane- 2,2-diyl)) bis(N-methyldithiocarbamate) is reacted at low temperature with various alkyl chloroformates to form various S-tert-alkyl-N,N- alkoxycarbonylmethyl-dithiocarbamate RAFT
A safe and efficient procedure to prepare alkyl and alkoxyalkyl chlorides and dichlorides by catalytic decomposition of the corresponding alkyl and alkoxyalkyl chloroformates and bischloroformates with hexabutylguanidinium chloride
Violleau,Thiebaud,Borredon,Le Gars
, p. 367 - 373 (2007/10/03)
Small amounts of hexabutylguanidinium chloride (0.01 mol%) decomposes pure chloroformates or bischloroformates with different lengths of carbon chains by a semicontinuous process to diminish run-away risk, leading to chloride compounds with high yield and purity.