5679-73-2Relevant articles and documents
PENTACO-ORDINATE PHOSPHORUS COMPOUNDS BY NUCLEOPHILIC ADDITION TO ACTIVATED ALKENES AND ALKYNES IN THE PRESENCE OF ALCOHOLS AND PHENOLS
Beer, Paul D.,Edwards, Robert C.,Hall, C. Dennis,Jennings, J. R.,Cozens, R. J.
, p. 283 - 296 (2007/10/02)
The reactions of a variety of trico-ordinate phosphorus compounds, ArnP(OR)3-n (n= 1 or 2), and cyclic analogues, with acrylonitrile, ethyl acrylate or ethyl phenylpropiolate and alcohols or phenols in low polarity media gives rise to a wide range of pentaco-ordinate phosphorus compounds.Attempts to extend this synthetic route to phosphoranes containing P-N or P-S bonds met with no success.