56986-56-2Relevant articles and documents
Twisted Thienylene–Phenylene Structures: Through-Space Orbital Coupling in Toroidal and Catenated Topologies
Leitner, Tanja D.,Gmeinder, Yannick,R?hricht, Fynn,Herges, Rainer,Mena-Osteritz, Elena,B?uerle, Peter
, p. 285 - 294 (2019/12/24)
Sterically crowded and twisted thienylene-phenylenes were synthesized and characterized in comparison to corresponding polyphenylene nanostructures. Spectroscopic, diffraction, and theoretical studies gave evidence of through-space delocalization of π-electrons of peripheral (hetero)aromatic rings in toroidal and catenated topologies.