5700-56-1Relevant articles and documents
Palladium-Catalyzed Intermolecular Oxidative Diazidation of Alkenes
Peng, Haihui,Yuan, Zheliang,Chen, Pinhong,Liu, Guosheng
supporting information, p. 876 - 880 (2017/06/27)
A palladium-catalyzed oxidative vicinal diazidation of alkenes has been developed, in which TMSN3 was used as azide source. Both styrenes and unactivated alkenes are suitable for this reaction. And trans-alkyldiazides were obtained as major products from cyclic alkenes with moderate to good diastereoselectivities. This reaction afforded an efficient way for the synthesis of useful 1,2-diamines after hydrogenation.
One-pot protocol to synthesize N-(β-nitro)amides by tandem Henry/Ritter reaction
Ai, Wensi,Shi, Ronghua,Zhu, Liyan,Jiang, Dehong,Ma, Xiaobo,Yuan, Jilan,Wang, Zhouyu
, p. 24044 - 24048 (2015/03/30)
A novel, efficient and atom economical one pot protocol for the synthesis of N-(β-nitro)amides has been described by combining the Henry reaction with the Ritter reaction. The designed products could be obtained from easily available aldehydes, nitroalkan
Iodine(III)-promoted intermolecular diamination of alkenes
Souto, Jose A.,Gonzalez, Yolanda,Iglesias, Alvaro,Zian, Debora,Lishchynskyi, Anton,Muniz, Kilian
supporting information; experimental part, p. 1103 - 1111 (2012/07/17)
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.