5729-92-0

Basic information

• Product Name: 1,2-Cyclohexanediol,1-methyl-4-(1-methylethyl)-,(1S,2R,4R)-
• CAS NO: 5729-92-0
• Molecular Weight: 172.268
• Mol File: 5729-92-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,2-Cyclohexanediol,1-methyl-4-(1-methylethyl)-,(1S,2R,4R)- (CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Cyclohexanediol,1-methyl-4-(1-methylethyl)-,(1S,2R,4R)- (5729-92-0)
• EPA Substance Registry System: 1,2-Cyclohexanediol,1-methyl-4-(1-methylethyl)-,(1S,2R,4R)- (5729-92-0)

Safety Data

• Hazardous Substances Data: 5729-92-0(Hazardous Substances Data)

Upstream product

• 61585-35-1 p-menth-1-ene 
• 1946-00-5 (1RS,2SR,4RS)-p-menth-8-ene-1,2-diol 
• 138-86-3 limonene. 
• 1195-92-2 Limonene oxide 
• 125627-55-6 (1S,2S,4R)-4-isopropyl-1-methyl-2-phenylselenenylcyclohexan-1-ol 
• 1195-31-9 (+)-p-menth-1-ene 
• 75-65-0 tert-butyl alcohol 
• 93861-30-4 (1S,2R,4R)-p-menthane-1,2,8-triol 
• 67-56-1 methanol 
• 59121-74-3 (1S,2R,4R)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 

Downstream Products

• 499-70-7 methyl-2 isopropyl-5 cyclohexanone 
• 2102-60-5 (+/-)-3,5-dinitro-benzoic acid-(trans-p-menth-6-en-2-yl ester) 

Relevant articles and documents

Diastereo and enantioselective synthesis of 1,2-diols promoted by electrophilic selenium reagents

Here we report the first example in which the phenylseleno group is directly substituted by a hydroxy function. The reaction is promoted by the PhSeOSO3H generated "in situ" by oxidation of (PhSe)2 with (NH4)2S2O8 at reflux in a 3:1 mixture of MeCN-H2O. I

Ruthenium Tetroxide Oxidation of Alkenes. A More Complete Picture

The ruthenium tetroxide oxidation of some linear and cyclic alkenes, representatives of five substitution patterns, has been performed in acetone-water (5:1) solution at -70 deg C using stoichiometric ammounts of the oxidant.The main reaction products are 1,2-diols and/or α-ketols depending on the nature of the substrate little amounts of scission products, aldehydes and/or carboxylic acids, are also obtained.Generally 1,2-diols predominate over α-ketols except in the oxidation of (-)-α-pinene that afforded the α-ketol in 51percent yield while no trace of the corresponding 1,2-diol was detected.All reactions prceeded through the formation of unstable brownish precipitates, presumably the intermediate ruthenium (VI) esters, which easily decomposed during the work-up step.Results from oxidation of trans-7-tetradecene and cis and trans-11-tetradecenyl acetate indicated that the reaction was syn stereospecific.In some cases, 1,3-dioxolane products, formed by condensation of the 1,2-diol and the aldehyde materials, were also obtained among the reaction products.Their possible origin is briefly discussed.