57415-83-5Relevant articles and documents
Rhodium-catalyzed anti-markovnikov-type hydrophosphination of terminal alkynes with diphosphines and hydrosilanes in the presence of oxygen
Kawaguchi, Shin-Ichi,Kotani, Mao,Ohe, Takashi,Nagata, Shoko,Nomoto, Akihiro,Sonoda, Motohiro,Ogawa, Akiya
, p. 1090 - 1097 (2010)
A novel rhodium(I)-catalyzed hydrophosphination of terminal alkynes with diphosphines and hydrosilanes takes place regioselectively in the presence of small amounts of oxygen. After air-oxidation during workups, the corresponding anti-Markovnikov-type vinylic phosphine oxides were obtained in good yields. Copyright Taylor & Francis Group.
Radical Hydrophosphorylation of Alkynes with R2P(O)H Generating Alkenylphosphine Oxides: Scope and Limitations
Huang, Tianzeng,Saga, Yuta,Guo, Haiqing,Yoshimura, Aya,Ogawa, Akiya,Han, Li-Biao
, p. 8743 - 8749 (2018/07/05)
Radical hydrophosphorylation of aliphatic terminal alkynes with H-phosphine oxides can produce the corresponding anti-Markovnikov alkenylphosphorus adducts in moderate yields. This method is a cleaner approach for the preparation of the corresponding alke
Selective addition of P(O)H bonds to alkynes catalyzed by transition metals immobilized on polystyrene-bound triphenylphosphine
Chen, Tieqiao,Zhou, Yongbo,Guo, Cancheng,Han, Li-Biao
, p. 1065 - 1067 (2013/09/24)
Addition of P(O)H bonds to alkynes catalyzed by transition metals (Rh, Pd, and Ni) immobilized on polystyrene-bound triphenylphosphine proceeded efficiently to afford high yields of the addition products with high regioselectivity. The immobilized catalys
