57740-07-5

Basic information

• Product Name: Cyclohexanebutanol, 1-hydroxy-
• CAS NO: 57740-07-5
• Molecular Formula: C10H20O2
• Molecular Weight: 172.268
• Mol File: 57740-07-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexanebutanol, 1-hydroxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanebutanol, 1-hydroxy-(57740-07-5)
• EPA Substance Registry System: Cyclohexanebutanol, 1-hydroxy-(57740-07-5)

Safety Data

• Hazardous Substances Data: 57740-07-5(Hazardous Substances Data)

Upstream product

• 14112-12-0 1-<1-Hydroxy-cyclohexyl>-butin-(1)-ol-(4) 
• 542-28-9 3,4,5,6-tetrahydro-2H-pyran-2-one 
• 23708-48-7 pentamethylenebis(magnesium bromide) 
• 849066-96-2 6-bromo-1-((3-buten-1-yl)dimethylsilyl)-1-hexanone 
• 4481-78-1 1-oxa-spiro[5.5]undecan-2-one 
• 32764-97-9 6-(but-3-en-1-yl)tetrahydro-2H-pyran-2-one 
• 108-94-1 cyclohexanone 
• 849066-88-2 [2-(5-Bromo-pentyl)-[1,3]dithian-2-yl]-but-3-enyl-dimethyl-silane 
• 108-95-2 phenol 
• 3210-08-0 4-iodo-butan-1-ol 
• 2651-46-9 (4-chlorobutoxy)benzene 
• 67-64-1 acetone 
• 630-19-3 pivalaldehyde 
• 100-52-7 benzaldehyde 

Downstream Products

• 4481-78-1 1-oxa-spiro[5.5]undecan-2-one 

Relevant articles and documents

The study of intramolecular tandem radical cyclizations of acylsilanes with radicalphiles attached on silicon

Radical cyclizations of acylsilanes with radicalphilic pendant introduced on silicon proceeded in a tandem fashion to give spiro products containing a cyclic silyl ether skeleton. Because the alkoxysilyl group can be replaced with a hydroxy group through

Grignard reagents: Alkoxide-directed iodine-magnesium exchange at sp 3 centers

(Chemical Equation Presented) Sequential addition of i-PrMgCl and BuLi to sp3 hybridized iodoalcohols triggers a facile iodine-metal exchange. Intercepting the resulting cyclic Grignard reagents with a slight excess of an electrophile leads to a diverse range of substituted alcohols. The iodine-magnesium exchange strategy is effective with 3-carbon iodoalcohols bearing alkyl substitutents on the carbinol or adjacent carbons and with the chain-extended homolog 4-iodobutan-1-ol.

Group transfer from silicon to carbon via tandem radical cyclizations of acylsilanes

Tandem radical cyclizations of acylsilanes with alkene or alkyne functionalities attached to silicon afforded cyclic silyl ethers which were oxidatively hydrolyzed to give diols or ketone alcohols.