5837-72-9

Basic information

• Product Name: FUMARALDEHYDIC ACID METHYL ESTER
• Synonyms: 3-(METHOXYCARBONYL)-2-PROPENAL;METHYL FUMARALDEHYDATE;FUMARALDEHYDIC ACID METHYL ESTER;FUMARALDEHYDIC ACID METHYL ESTER 95+%;3-(Methoxycarbonyl)-2-propenal Fumaraldehydic Acid Methyl Ester 3-(Methoxycarbonyl)acrylaldehyde;methyl (E)-4-oxobut-2-enoate;3-(METHOXYCARBONYL)ACRYLALDEHYDE
• CAS NO: 5837-72-9
• Molecular Formula: C₅H₆O₃
• Molecular Weight: 114.1
• Mol File: 5837-72-9.mol
• Article Data: 12

Chemical Properties

• Melting Point: 40 °C
• Boiling Point: 88 °C / 40mmHg
• Appearance: /
• Density: 1.081±0.06 g/cm3(Predicted)
• Storage Temp.: Refrigerator
• CAS DataBase Reference: FUMARALDEHYDIC ACID METHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: FUMARALDEHYDIC ACID METHYL ESTER(5837-72-9)
• EPA Substance Registry System: FUMARALDEHYDIC ACID METHYL ESTER(5837-72-9)

Safety Data

• Hazardous Substances Data: 5837-72-9(Hazardous Substances Data)

Usage

Description

Fumaraldehydic acid methyl ester, also known as methyl fumaraldehyde, is a colorless liquid chemical compound with the molecular formula C5H6O3. It has a fruity odor and is commonly used as a flavoring agent in the food and beverage industry. Additionally, it is utilized in the production of perfumes and serves as a chemical intermediate in the synthesis of other organic compounds. Fumaraldehydic acid methyl ester is relatively stable and has low toxicity, but it should be handled with care and in accordance with proper safety protocols.

Uses

Used in Food and Beverage Industry:
Fumaraldehydic acid methyl ester is used as a flavoring agent to impart a fruity aroma and taste to various food and beverage products.
Used in Perfume Production:
Fumaraldehydic acid methyl ester is used as a component in the production of perfumes, contributing to the creation of unique and pleasant fragrances.
Used in Chemical Synthesis:
Fumaraldehydic acid methyl ester serves as a chemical intermediate in the synthesis of other organic compounds, playing a crucial role in the development of new chemical products.

Upstream product

• 623-43-8 crotonic acid methyl ester 
• 1515-80-6 sorbic acid methyl ester 
• 689-89-4 (2E,4E)-methylhexa-2,4-dienoate 
• 623-43-8 methyl crotonate 
• 67-56-1 methanol 
• 31004-27-0 3-chlorofuran-2(5H)-one 
• 57314-32-6 methyl (Z)-4-oxobut-2-enoate 
• 4437-06-3 trans-β-formylacrylic acid 
• 74-88-4 methyl iodide 
• 29576-13-4 methyl 4-hydroxy-2-butenoate 
• 166819-46-1 Methyl (Z)-4-hydroperoxy-4-methoxy-2-butenoate 
• 32815-00-2 monofumaraldehyde dimethylacetal monomethylester 
• 53892-48-1 (2Z,4Z)-hexadienoic acid methyl ester 
• 6932-46-3 (2Z,4E)-hexadienoic acid methyl ester 

Downstream Products

• 62222-81-5 (E)-methyl 4-cyclohexylidenebut-2-enoate 
• 5460-63-9 methyl (dl)-trans-chrysanthemate 
• 25090-19-1 methyl (2E,4E)-6-(4-methoxyphenyl)-2,4-hexadienoate 
• 2756-87-8 methyl hydrogen fumarate 
• 77823-89-3 methyl 2β-formyl-3β<(benzyloxycarbonyl)amino>-4-cyclohexene-α-carboxylate 
• 78839-85-7 (E)-4-Hydroxy-4-[2-(2,2,2-trifluoro-acetylamino)-phenyl]-but-2-enoic acid methyl ester 
• 135075-62-6 (4RS,5RS)-(E)-3-(1,3,4,5-Tetraphenylimidazolidin-2-yl)propenoate 
• 131570-77-9 Methyl (E)-3-<4(S)-3-Benzyl-4-isopropyloxazolidin-2-yl>propenoate 
• 137089-48-6 (2S,3S,4S)-3-(2-Benzyloxy-ethyl)-2-heptyloxy-3,4-dihydro-2H-pyran-4-carboxylic acid methyl ester 
• 135075-64-8 Methyl (4RS,5RS)-(E)-3-(1,3-Dimethyl-4,5-diphenylimidazolidin-2-yl)propenoate 
• 135075-64-8 Methyl (4S,5S)-(-)-(E)-3-(1,3-Dimethyl-4,5-diphenylimidazolidin-2-yl)propenoate 
• 135212-29-2 Methyl (4R,5R)-(+)-(E)-3-(1,3-Dimethyl-4,5-diphenylimidazolidin-2-yl)propenoate 
• 135075-62-6 (4R,5R)-(+)-(E)-3-(1,3,4,5-Tetraphenylimidazolidin-2-yl)propenoate 
• 135075-63-7 (4S,5S)-(-)-(E)-3-(1,3,4,5-Tetraphenylimidazolidin-2-yl)propenoate 

Relevant articles and documents

Macrocyclisation of macrodiolide with dimethylaluminium methaneselenolate

Dimethylaluminium methaneselenolate (Me2AlSeMe, 1) acts as an acyl transfer agent for esterification. In cases of direct macrolactonisation (n = 10-12), this selenium-aluminium complex preferentially creates symmetric macrodiolides rather than macrolides. The factors determining macrodilactonisation were investigated and applied toward the total synthesis of norpyrenophorin, which result in a macrodilactonisation yield of 64 %. Dimethylaluminium methaneselenolate (Me2AlSeMe, 1) acts as an acyl transferagent for esterification. In cases of direct macrolactonisation (n = 10-12), this selenium-aluminium complex preferentiallycreates symmetric macrodiolides rather than macrolides. The factors determining macrodilactonisation were investigated and applied toward the total synthesis of nor-pyrenophorine. Copyright

Photochemical studies on ladderane formation from conjugated esters in solution or solid phase

This letter describes a combined photochemical and X-ray crystallographic study of routes for the synthesis of cyclobutane or ladderane structures by a [2+2]-cycloaddition pathway and leads to a clearer definition of the 3-D structural requirements for su

Chloroperoxidase-catalyzed oxidation of conjugated dienoic esters

The chloroperoxidase (CPO)-catalyzed oxidations of dienes conjugated to an ester group were studied using tert-butyl hydroperoxide as the terminal oxidant.