5840-78-8

Basic information

• Product Name: N-[3-(benzoylamino)phenyl]-5-bromonaphthalene-1-carboxamide
• CAS NO: 5840-78-8
• Molecular Formula: C₉H₇NO₃
• Molecular Weight: 445.308
• Mol File: 5840-78-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 481.5°C at 760 mmHg
• Flash Point: 245°C
• Density: 1.496g/cm³
• Vapor Pressure: 1.98E-09mmHg at 25°C
• Refractive Index: 1.747
• CAS DataBase Reference: N-[3-(benzoylamino)phenyl]-5-bromonaphthalene-1-carboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[3-(benzoylamino)phenyl]-5-bromonaphthalene-1-carboxamide(5840-78-8)
• EPA Substance Registry System: N-[3-(benzoylamino)phenyl]-5-bromonaphthalene-1-carboxamide(5840-78-8)

Safety Data

• Hazardous Substances Data: 5840-78-8(Hazardous Substances Data)

Upstream product

• 60733-91-7 methoxycarbonylamino-phenyl-acetic acid 
• 2835-06-5 phenylglycin 
• 75-44-5 phosgene 
• 75247-41-5 N-Trimethylsilyl-DL-2-phenylglycin-trimethylsilylester 
• 32315-10-9 bis(trichloromethyl) carbonate 

Downstream Products

• 53059-79-3 2-{[1-(4-Methoxy-phenyl)-meth-(E)-ylidene]-amino}-N-methyl-2-phenyl-acetamide 
• 55153-97-4 3-(2-nitro-phenylsulfanyl)-4-phenyl-oxazolidine-2,5-dione 
• 53128-97-5 3-Phenyl-2-(2-phenyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-acetylamino)-propionic acid methyl ester 
• 142955-51-9 4-Benzyl-2,5-dioxo-oxazolidine-3-carboxylic acid tert-butyl ester 
• 470670-74-7 2,5-dioxo-4-phenyl-oxazolidine-3-carboxylic acid 9H-fluoren-9-ylmethyl ester 
• 394210-43-6 2,5-dioxo-4-phenyl-oxazolidine-3-carboxylic acid benzyl ester 
• 17609-52-8 Z-D-phenylglycine 
• 64286-85-7 N-<(phenylmethoxy)carbonyl>-L-phenylalanine 2-propenyl ester 
• 219323-43-0 (S)-ethyll 2-(benzyloxycarbonylamino)-2-phenylacetate 
• 470670-75-8 (R)-allyl-(N-benzyloxycarbonyl)phenylglycinate 
• 5491-18-9 (S)-N-(benzyloxycarbonyl)phenylglycine 
• 117402-99-0 Piv-DL-Phg-NHi-Pr 
• 117402-99-0 Piv-L-Phg-NHi-Pr 
• 117402-99-0 Piv-D-Phg-NHi-Pr 

Relevant articles and documents

Development of a rapid, room-temperature dynamic kinetic resolution for efficient asymmetric synthesis of α-aryl amino acids

equation presented A rapid, highly efficient and general dynamic kinetic resolution (DKR) of racemic α-aryl UNCAs with the dual-function catalysis of modified cinchona alkaloid was accomplished at room temperature. This DKR led to the development of a highly enantioselective catalytic method for the practical synthesis of a wide range of α-aryl and α-heteroaryl amino acids in 89-92% ee and 86-95% yield from racemic UNCAs.

ENANTIOMERIC QUANTIFICATIONS OF AMINO ACIDS THROUGH THEIR Nα-ACYL AMIDES BY GAS CHROMATOGRAPHY.

Apparent separation of 1.1 or higher on Chiralsil Val III can be obtained for Nα-acyl N-alkyl aminoacid amides allowing the use of short capillary gas chromatographic columns.A clean derivatization protocol without racemization is described, proceding through the NCA derivatives that are prepared from "in situ" silylated amino acids with trimethylsilyl cyanide.