58491-62-6Relevant articles and documents
Catalytic Amidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxamide over Alkali Manganese Oxides
Li, Xiaofang,Jia, Xiuquan,Ma, Jiping,Xu, Yongming,Huang, Yizheng,Xu, Jie
, p. 984 - 990 (2017)
2,5-Furandicarboxamide was firstly synthesized in yield of 85% via catalytic oxidative amidation of 5-hydroxymethylfurfural with aqueous NH3 over alkali manganese oxides of α-MnO2/NaxMnO2. The intermediates of 5-hydroxymethyl-furonitrile, 2,5-dicyanofuran, and 5-cyano-2-furancarboxamide were verified and their reactivities were further examined. The kinetic analysis results showed that the transformation of intermediate product of 5-cyano-2-furancarboxamide to 2,5-furan-dicarboxamide is a slower step, which is closely relative to the reaction temperature and basicity of catalyst.
Preparation method of 2, 5-dicyanofuran
-
Paragraph 0049-0080, (2020/11/05)
The invention discloses a preparation method of 2, 5-dicyanofuran, and the method comprises the following steps: in the presence of an oxidant, reacting a mixture containing 2, 5-diformyl furan, a nitrogen source and a catalyst to obtain the 2, 5-dicyanofuran, wherein the catalyst comprises a metal oxide modified by an organic compound. According to the method for preparing the 2, 5-dicyanofuran through efficient catalytic ammoxidation of the 2, 5-diformyl furan provided by the invention, high-quality 2, 5-dicyanofuran is prepared through high-selectivity ammoxidation of the 2, 5-diformyl furan under mild conditions. The method is high in oxidation efficiency and high in product yield; air or oxygen serves as an oxygen source, ammonium salt serves as the nitrogen source, and the nitrogen source is high in utilization rate, clean and environment-friendly; the product and the catalyst are easy to separate, the post-treatment is simple, and the application prospect is good.
Method for continuous preparation of nitriles by amides (by machine translation)
-
Paragraph 0033-0054; 0061-0066, (2020/12/15)
The method comprises the following steps: preparing a lead salt supported by a molecular sieve by a lead salt and a molecular sieve through an impregnation method; and filling a molecular sieve-loaded lead catalyst into a fixed bed reactor. The amide or amide solution is sent into a fixed bed reactor from the top of the fixed bed to be subjected to catalytic dehydration, and the obtained reaction product is led out from the bottom of the fixed bed. The reaction product is separated to obtain the crude product of the nitrile corresponding to the amide. A fixed bed continuous production process is adopted, the reaction process is simple, the production efficiency is high, the product post-treatment is simple, and industrial production is easy to realize. (by machine translation)