58518-77-7

Basic information

• Product Name: Silane, [[1-(4-fluorophenyl)ethenyl]oxy]trimethyl-
• Synonyms: [1-(4-fluorophenyl)vinyloxy]trimethylsilane;1-Fluoro-4-[1-[(trimethylsilyl)-oxy]ethenyl]-benzene;Silane,[[1-(4-fluorophenyl)ethenyl]oxy]trimethyl
• CAS NO: 58518-77-7
• Molecular Formula: C11H15FOSi
• Molecular Weight: 210.323
• Mol File: 58518-77-7.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Silane, [[1-(4-fluorophenyl)ethenyl]oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[1-(4-fluorophenyl)ethenyl]oxy]trimethyl-(58518-77-7)
• EPA Substance Registry System: Silane, [[1-(4-fluorophenyl)ethenyl]oxy]trimethyl-(58518-77-7)

Safety Data

• Hazardous Substances Data: 58518-77-7(Hazardous Substances Data)

Upstream product

• 403-42-9 1-(4-fluorophenyl)ethanone 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 2857-97-8 trimethylsilyl bromide 
• 75-77-4 chloro-trimethyl-silane 
• 144-55-8 sodium hydrogencarbonate 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 159429-78-4 1-(4-Fluoro-phenyl)-3,3-dimethyl-5-(4-methylsulfanyl-phenyl)-pentane-1,5-dione 
• 159429-81-9 3,3-Diethyl-1-(4-fluoro-phenyl)-5-(4-methylsulfanyl-phenyl)-pentane-1,5-dione 
• 159429-80-8 1-(4-Fluoro-phenyl)-5-(4-methylsulfanyl-phenyl)-3,3-bis-trifluoromethyl-pentane-1,5-dione 
• 139214-37-2 [2-(4-fluorophenyl)allyl]trimethylsilane 
• 35444-02-1 4,4,4-Trifluoro-1-(4-fluoro-phenyl)-3-trifluoromethyl-but-2-en-1-one 
• 143211-32-9 4,4,4-Trifluoro-1-(4-fluoro-phenyl)-3-hydroxy-3-trifluoromethyl-butan-1-one 
• 189028-93-1 (S)-1-(4-fluorophenyl)-5-(2-oxo-4-phenyloxazolidin-3-yl)pentane-1,5-dione 
• 69746-38-9 5-(4-fluorophenyl)-2,3-dihydrofuran-2,3-dione 
• 66267-01-4 [1-(4-Fluoro-phenyl)-cyclopropoxy]-trimethyl-silane 
• 654674-77-8 1-(4-fluorophenyl)-2-(piperidin-1-ylsulfonyl)ethan-1-one 
• 405-99-2 para-fluorostyrene 

Relevant articles and documents

Versatile and base-free copper-catalyzed α-arylations of aromatic ketones using diaryliodonium salts

A ligand and base-free copper catalyzed synthetic method for the efficient α-arylation of aromatic ketones is described. In order to avoid strong bases, ketone-derived silyl enol ethers were employed. Their reaction with diaryliodonium salts as aryl source provided the intermolecular C–C coupling displaying good functional group tolerance and requiring low catalyst loading.

Lewis Acid-Catalyzed Carbofunctionalization of Uncommon C, N-Diacyliminium Ions: Controlling Regio- And Enantioselectivity

The tricyclic azepino[1,2-a]indole acetates 7, readily accessible by visible-light-driven catalytic photooxygenation of cyclohepta[b]indoles 1, are convenient precursors to novel and uncommon cyclic C,N-diacyliminium ions 3. We report here the first Lewis

Defluorinative Ring-Opening Indolylation of Siloxydifluorocyclopropanes: Controlled Synthesis of α-Fluoro-β-Indolyl-Propanones for Carbazole Construction

A catalytic defluorinative ring-opening indolylation of siloxydifluorocyclopropanes was reported. It was found that AgBF4-catalyzed reaction of siloxydifluorocyclopropanes with indoles could be controlled to deliver α-fluoro-β-indolyl-propanones within 1.5 hours at room temperature. Cyclization of these α-fluoroketone derivatives were then carried out in the presence of trifluoroacetic anhydride in toluene at room temperature. Carbazoles were formed efficiently via an intramolecularly nucleophilic addition of the in situ formed enamine intermediate to the keto carbonyl, followed by a sequential hydrolysis and eliminations of trifluoroacetic acid and hydrogen fluoride. (Figure presented.).