594822-19-2

Basic information

• Product Name: Benzene, [1-methyl-1-[(2-methyl-2-propenyl)oxy]-3-butenyl]-
• CAS NO: 594822-19-2
• Molecular Formula: C15H20O
• Molecular Weight: 216.323
• Mol File: 594822-19-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [1-methyl-1-[(2-methyl-2-propenyl)oxy]-3-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-methyl-1-[(2-methyl-2-propenyl)oxy]-3-butenyl]-(594822-19-2)
• EPA Substance Registry System: Benzene, [1-methyl-1-[(2-methyl-2-propenyl)oxy]-3-butenyl]-(594822-19-2)

Safety Data

• Hazardous Substances Data: 594822-19-2(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 4743-74-2 2-phenylpent-4-en-2-ol 
• 563-47-3 3-Chloro-2-methylpropene 

Downstream Products

• 251301-50-5 2,5-dimethyl-2-phenyl-3,6-dihydro-2H-pyran 

Relevant articles and documents

Synthesis of conjugated γ- and δ-lactones from aldehydes and ketones via a vinylation(allylation)-ring closing metathesis-oxidation sequence

Nucleophilic C-vinylation and C-allylation of aldehydes and ketones followed by O-allylation of the obtained carbinols gave the corresponding allyl or homoallyl ethers, respectively. Ring-closing metathesis of these compounds afforded in many cases cyclic ethers (dihydrofurans and dihydropyrans, respectively) bearing disubstituted and trisubstituted C=C bonds. These were then subjected to allylic oxidation to yield conjugated γ- and δ-lactones. Reasons for the observed failures are presented and discussed.