60018-13-5

Basic information

• Product Name: (3R)-3,7-Dimethyl-1-octanone
• Synonyms: (3R)-3,7-Dimethyl-1-octanone;(3R)-3,7-Dimethyloctanal;(R)-3,7-Dimethyloctanal;[R,(+)]-3,7-Dimethyloctanal
• CAS NO: 60018-13-5
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.27
• Mol File: 60018-13-5.mol
• Article Data: 65

Chemical Properties

• Boiling Point: 31-33 °C(Press: 0.15 Torr)
• Appearance: /
• Density: 0.815±0.06 g/cm3(Predicted)
• CAS DataBase Reference: (3R)-3,7-Dimethyl-1-octanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3R)-3,7-Dimethyl-1-octanone(60018-13-5)
• EPA Substance Registry System: (3R)-3,7-Dimethyl-1-octanone(60018-13-5)

Safety Data

• Hazardous Substances Data: 60018-13-5(Hazardous Substances Data)

Upstream product

• 5392-40-5 (E/Z)-3,7-dimethyl-2,6-octadienal 
• 54631-71-9 3,7-dimethylocta-2,4,6-trienal 
• 57784-35-7 3,7-dimethyl-2-octenal 
• 106-22-9 Citronellol 
• 106-21-8 tetrahydrogeraniol 
• 106-23-0 3,7-dimethyl-oct-6-enal 
• 1117-61-9 (3R)-citronellol 
• 106-24-1 Geraniol 
• 141-27-5 3,7-dimethyl-2,6-octadienal 
• 111-42-2 2,2'-iminobis[ethanol] 
• 64-17-5 ethanol 
• 2385-77-5 (R)-Citronellal 
• 5713-07-5 3,7-dimethyl-oct-7-en-1-ol 
• 63539-99-1 8-acetoxy-6-methyloctan-2-one 

Downstream Products

• 63048-82-8 [2-(2,6-Dimethyl-heptyl)-cyclobut-1-enylsulfanyl]-benzene 
• 93813-63-9 (+)-2-Anilino-4,8-dimethyl-nonansaeure-nitril 
• 77331-35-2 5-(3,7-Dimethyl-octyl)-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide 
• 41096-47-3 Ethyl-3,7,11-Trimethyl-cis-2,trans-4-dodecadienoat 
• 41096-46-2 hydroprene 
• 36557-30-9 (S)-hydroprene 
• 41096-45-1 ?(E)-6,10-dimethylundec-3-en-2-one 
• 65147-64-0 2-(2,6-dimethylheptyl)cyclobutanone 
• 106-21-8 tetrahydrogeraniol 
• 63048-73-7 3,7-Dimethyl-1-(1-phenylsulfanyl-cyclopropyl)-octan-1-ol 
• 80957-85-3 4E ethyl 7,11-dimethyl-3-oxododec-4-enoate 
• 72962-76-6 3E 6,10-dimethyl-3-undecen-2-one 
• 32531-52-5 3,7-dimethyloctanoic acid 

Relevant articles and documents

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

Catalytic Access to Functionalized Allylic gem-Difluorides via Fluorinative Meyer–Schuster-Like Rearrangement

An unprecedented approach for efficient synthesis of functionalized allylic gem-difluorides via catalytic fluorinative Meyer–Schuster-like rearrangement is disclosed. This transformation proceeded with readily accessible propargylic fluorides, and low-cost B–F reagents and electrophilic reagents by sulfide catalysis. A series of iodinated, brominated, and trifluoromethylthiolated allylic gem-difluorides that were difficult to access by other methods were facilely produced with a wide range of functional groups. Importantly, the obtained iodinated products could be incorporated into different drugs and natural products, and could be expediently converted into many other valuable gem-difluoroalkyl molecules as well. Mechanistic studies revealed that this reaction went through a regioselective fluorination of alkynes followed by a formal 1,3-fluorine migration under the assistance of the B–F reagents to give the desired products.

Fine-Bubble-Slug-Flow Hydrogenation of Multiple Bonds and Phenols

We describe a promising method for the continuous hydrogenation of alkenes or alkynes by using a newly developed fine-bubble generator. The fine-bubble-containing slug-flow system was up to 1.4 times more efficient than a conventional slug-flow method. When applied in the hydrogenation of phenols to the corresponding cyclohexanones, the fine bubble-slug-flow method suppressed over-reduction. As this method does not require the use of excess gas, it is expected to be widely applicable in improving the efficiency of gas-mediated flow reactions.