60623-60-1Relevant articles and documents
Method for decarboxylation generation C-S key of active ester compound
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Paragraph 0029-0036, (2021/09/21)
To an aspect of the present invention, there is provided a method of decarboxylation-generating C-S bonds by using an active ester compound in which the general formula is R under light irradiation. a Active ester of - COONPhth and general form
Visible-light induced decarboxylative coupling of redox-active esters with disulfides to construct C-S bonds
Xiao, Zhiwei,Wang, Lu,Wei, Junjie,Ran, Chongzhao,Liang, Steven H.,Shang, Jingjie,Chen, Guang-Ying,Zheng, Chao
supporting information, p. 4164 - 4167 (2020/04/22)
A novel method has been established for the construction of C-S bonds using redox-active esters with disulfides in the presence of Ru-photoredox catalyst. This method exhibits remarkable functional group tolerance across a wide scope of substrates. Under
Efficient C?S Bond Formation by Direct Functionalization of C(sp3)?H Bond Adjacent to Heteroatoms under Metal-Free Conditions
Zhao, Feng,Tan, Qi,Wang, Dahan,Chen, Jinjin,Deng, Guo-Jun
supporting information, p. 4075 - 4081 (2019/08/01)
A simple and efficient method for the formation of C?S bond via direct functionalization of C(sp3)?H bond adjacent to heteroatoms was described under metal-free conditions. In this work, stable and easily accessible sodium sulfinates were used as the thiolating agents to afford various aryl thioethers in moderate to excellent yields. Mechanistic explorations show that a radical pathyway is possibly involved during the transformations. (Figure presented.).