60883-93-4

Basic information

• Product Name: 5-azidophenanthroline
• Synonyms: 5-azidophenanthroline
• CAS NO: 60883-93-4
• Molecular Weight: 219.246
• Mol File: 60883-93-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-azidophenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 5-azidophenanthroline(60883-93-4)
• EPA Substance Registry System: 5-azidophenanthroline(60883-93-4)

Safety Data

• Hazardous Substances Data: 60883-93-4(Hazardous Substances Data)

Upstream product

• 68572-87-2 9-phenanthrenylboronic acid 

Downstream Products

• 1529-40-4 9H-fluorene-9-carbonitrile 
• 947-73-9 9-Aminophenanthrene 
• 141606-44-2 fluorene-4-carbonitrile 
• 85-01-8 phenanthrene 

Relevant articles and documents

Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer

An enantioselective, radical-based method for the intramolecular hydroamination of alkenes with sulfonamides is reported. These reactions are proposed to proceed via N-centered radicals formed by proton-coupled electron transfer (PCET) activation of sulfonamide N-H bonds. Noncovalent interactions between the neutral sulfonamidyl radical and a chiral phosphoric acid generated in the PCET event are hypothesized to serve as the basis for asymmetric induction in a subsequent C-N bond forming step, achieving selectivities of up to 98:2 er. These results offer further support for the ability of noncovalent interactions to enforce stereoselectivity in reactions of transient and highly reactive open-shell intermediates.