6090-09-1 Usage
Description
4-Acetyl-1-methyl-1-cyclohexene, also known as 1-(4-methyl-3-cyclohexen-1-yl)ethanone, is an organic compound that is characterized by its distinct chemical structure and properties. It is an essential oil that can be found in various natural sources, such as Cedrus atlantica wood and orange peels. 4-Acetyl-1-methyl-1-cyclohexene is known for its unique aroma and potential applications in various industries.
Uses
Used in Fragrance Industry:
4-Acetyl-1-methyl-1-cyclohexene is used as a fragrance ingredient for its distinctive scent. 4-Acetyl-1-methyl-1-cyclohexene is valued for its ability to add depth and complexity to perfumes, colognes, and other scented products. Its natural occurrence in Cedrus atlantica wood and orange peels contributes to its appeal as a component in the creation of various fragrances.
Used in Flavor Industry:
In addition to its applications in the fragrance industry, 4-Acetyl-1-methyl-1-cyclohexene is also used as a flavoring agent. Its unique taste and aroma make it a valuable addition to the flavor profiles of various food and beverage products. 4-Acetyl-1-methyl-1-cyclohexene can be used to enhance the flavor of citrus-based products, as well as other applications where a subtle, yet distinct, flavor is desired.
Used in Essential Oils:
4-Acetyl-1-methyl-1-cyclohexene is used as a component in essential oils, which are widely used for their therapeutic and aromatic properties. 4-Acetyl-1-methyl-1-cyclohexene's presence in essential oils derived from Cedrus atlantica wood and orange peels contributes to their overall scent and potential benefits. These essential oils can be used in aromatherapy, massage, and other applications where their therapeutic properties are sought after.
Used in Research and Development:
Due to its unique chemical structure and properties, 4-Acetyl-1-methyl-1-cyclohexene is also used in research and development for various applications. Scientists and researchers may utilize this compound in the development of new materials, pharmaceuticals, or other products that can benefit from its specific characteristics.
Purification Methods
Purify it by fractionation under reduced pressure in vacuo, and if it is almost pure it can be fractionated at atmospheric pressure, preferably in an inert atmosphere. It forms two semicarbazones one of which is more soluble in *C6H6, and both can be recrystallised from EtOH; the more soluble has m 149o(151o), and the less soluble has m 172-175o(191o). The 4-nitrophenylhydrazone has m 166-167o and the 2,4-dinitrophenylhydrazone has m 114-115o. [Pfau & Plattner Helv Chim Acta 17 129, 142 1934, Adler & Vogt Justus Liebigs Ann Chem 564 109 1949.]
Check Digit Verification of cas no
The CAS Registry Mumber 6090-09-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,0,9 and 0 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 6090-09:
(6*6)+(5*0)+(4*9)+(3*0)+(2*0)+(1*9)=81
81 % 10 = 1
So 6090-09-1 is a valid CAS Registry Number.
InChI:InChI=1/C9H14O/c1-7-3-5-9(6-4-7)8(2)10/h3,9H,4-6H2,1-2H3
6090-09-1Relevant articles and documents
Lutz,Bailey
, p. 3899 (1964)
Viable route and DFT study for the synthesis of optically active limonaketone: A barely available natural feedstock in Cedrus atlantica
Mekkaoui, Ayoub Abdelkader,Ben El Ayouchia, Hicham,Anane, Hafid,Chahboun, Rachid,El Firdoussi, Larbi,El Houssame, Soufiane
, (2021/03/24)
Herein, we report a novel, easy and efficient synthesis pathway of optically active limonaketone, a high added value monoterpene, starting from limonene, natural and low-cost feedstock. The strategy was developed in an excellent three-step total synthesis of limonaketone, potentially important intermediate in limonene ozonolysis and barely available in Cedrus atlantica essential oil (0.1% yield). The first step was the epoxidation of limonene which proceed in 91% yield. The ozonolysis of the prepared limonene oxide leads to the formation of the characteristic ketone function of limonaketone in 92% yield. The last step was performed by a deoxygenation in the presence of Zn and gave limonaketone in quantitative yield. The optically pure limonaketone has been efficiently synthesized from limonene and the overall yield was 84%. A molecular electron density theory (MEDT) analysis was carried out by using density functional theory (DFT) calculations at the M06–2X/6–311G(d,p) (LANL2DZ for Zn) level to understand the observed chemoselectivity in the Zn-deoxygenation reaction as well as its corresponding mechanistic pathway.
Identification of the early intermediates formed in ozonolysis of: Cis-2-butene and limonene: A theoretical and matrix isolation study
Li, Shan-Shan,Yang, Xiao-Yang,Xu, Yi-Sheng,Jiang, Lei
, p. 20100 - 20106 (2019/07/09)
This study combined quantum chemical calculations and the matrix isolation technique to identify the formation of primary intermediates from the ozonolysis of cis-2-butene and limonene. Quantum chemical calculations were conducted under the framework of density functional theory (DFT) at M06-2x/6-311+(d, p) level of theory to predict the possible mechanism as well as the new absorption bands. New bands whose intensity increased with annealing, were observed in twin jet deposition, which indicated the formation of primary ozonides, CI and secondary ozonides in the investigated systems. Isotopic labeling (18O) experiments further supported the assignment of observed bands. The results and findings in this study would enrich the understanding of the reaction mechanism of alkene ozonolysis.