60930-56-5Relevant articles and documents
Preparation of azoxy benzene (by machine translation)
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Paragraph 0029; 0040, (2020/05/21)
[A] good workability and safety, cost, and, efficient production of the azoxy benzene azoxy benzene can be produced. [Solution] nitrobenzene ones, having the photocatalytic function with a dye, a reducing agent such as a fluorine resin or a transparent resin material is a mixed solution of 1 mm in diameter are inserted into the tube 4 does not inhibit the reaction, 4 LED lamp 5 emits visible from the outside of the tube moves within the tube 4 is provided with visible light within the tube 4 by a photocatalyst reaction mixed solution so as to obtain azoxy benzene compounds. Figure 2 [drawing] (by machine translation)
Oxidation of dichloroanilines and related anilides catalyzed by iron(III) tetrasulfonatophthalocyanine
Hadasch, Anke,Meunier, Bernard
, p. 2319 - 2325 (2007/10/03)
We investigated the degradation of polychlorinated pollutants, such as dichloroanilines and related anilides, catalyzed by iron(III) tetrasulfonatophthalocyanine (FePcS) with potassium monopersulfate or hydrogen peroxide as oxidant. The reaction is influenced by the positions of the two chloro-substituents and by the nature of the oxidant. The FePcS- catalyzed oxidation of 3,5-dichloroaniline with potassium monopersulfate leads to the formation of more biodegradable products (carboxylic acids) and to potentially toxic dimers (azo and azoxy compounds). The oxidation of 3,4- dichloroaniline by FePcS/H2O2 converts this pollutant into coupling products. The formation of dimers in the catalytic oxidation of dichloroanilines can be avoided by acylation of the amine function.