61077-65-4

Basic information

• Product Name: 2-Phenyl-4-penten-2-ol
• CAS NO: 61077-65-4
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.232
• Mol File: 61077-65-4.mol
• Article Data: 79

Chemical Properties

• Boiling Point: 257.6°Cat760mmHg
• Flash Point: 108.9°C
• Density: 0.981g/cm³
• CAS DataBase Reference: 2-Phenyl-4-penten-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-4-penten-2-ol(61077-65-4)
• EPA Substance Registry System: 2-Phenyl-4-penten-2-ol(61077-65-4)

Safety Data

• Hazardous Substances Data: 61077-65-4(Hazardous Substances Data)

Upstream product

• 122-78-1 phenylacetaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 4436-24-2 1,2-epoxy-3-phenylpropane 
• 104747-24-2 (vinyl)Cu*BF₃ 
• 7393-43-3 tetraallyl tin 
• 24850-33-7 allyltributylstanane 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 
• 101-48-4 phenylacetaldehyde dimethyl acetal 
• 4861-85-2 isopropyl phenylacetate 
• 101-97-3 Ethyl 2-phenylethanoate 
• 101-41-7 benzeneacetic acid methyl ester 
• 917-57-7 vinyllithium 
• 96-09-3 styrene oxide 

Downstream Products

• 202933-83-3 Allyl-(1-benzyl-but-3-enyloxy)-dimethyl-silane 
• 1150312-94-9 (R)-1-phenylpent-4-en-2-yl acetate 
• 122332-14-3 (S)-1-phenylpent-4-en-2-ol 
• 1229346-86-4 (R)-6-benzyl-5,6-dihydro-2H-pyran-2-one 
• 493-92-5 Prolintane 
• 345895-24-1 1-phenyl-2-(octyloxy)-4-pentene 
• 873872-93-6 1-phenylpent-4-en-2-yl (E,E)-di(propen-1-yl)phosphinate 
• 81096-91-5 (±)-4-phenylbutane-1,3-diol 

Relevant articles and documents

Stereospecific Intramolecular Reductive Cross-Electrophile Coupling Reactions for Cyclopropane Synthesis

The stereospecific reductive cross-electrophile coupling reaction of 2-aryl-4-chlorotetrahydropyrans to afford disubstituted cyclopropanes is reported. This ring contraction presents surprises with respect to the stereochemical outcome of reaction of the

Triphosgene-pyridine mediated stereoselective chlorination of acyclic aliphatic 1,3-diols

We describe a strategy to chlorinate stereocomplementary acyclic aliphatic 1,3-diols using a mixture of triphosgene and pyridine. While 1,3-anti diols readily led to 1,3-anti dichlorides, 1,3-syn diols must be converted to 1,3-syn diol monosilylethers to access the corresponding 1,3-syn dichlorides. These dichlorination protocols were operationally simple, very mild, and readily tolerated by advanced synthetic intermediates.

Allylation and propargylation of aldehydes mediated byin situgenerated zinc from the redox couple of Al and ZnCl2in 2N HCl

A simple one pot allylation and propargylation of aldehydes mediated by zinc(0), which isin situgenerated from the redox couple of Al and ZnCl2in 2N HCl, is demonstrated to afford the corresponding homoallyl and homopropargyl alcohols with exce

Ni-Catalyzed 1,2-Diarylation of Alkenyl Ketones: A Comparative Study of Carbonyl-Directed Reaction Systems

A nickel-catalyzed 1,2-diarylation of alkenyl ketones with aryl iodides and arylboronic esters is reported. Ketones with a variety of substituents serve as effective directing groups, offering high levels of regiocontrol. A representative product is diversified into a wide range of useful products that are not readily accessible via existing 1,2-diarylation reactions. Preliminary mechanistic studies shed light on the binding mode of the substrate, and Hammett analysis reveals the effect of electronic factors on initial rates.